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LLC (Logical Link Control) layer in 802.2. These are sublayers of the OSI data link layer (Layer 2). The two layers were defined separately to provide additional link control features and so that common LLC frames could be used for different media types, such as Ethernet, Token-Ring, and Fiber Distributed Data Interface (FDDI). This allows bridging at Layer 2 between the different media types. There are three different 802.3 formats that were used for older protocols such as Novel Netware s IPx and Apple Computer s Appletalk protocols and OSI protocols. Today, these formats are rarely used. The Alcatel-Lucent 7750 SR uses the 802.3 format for the transmission of IS IS routing updates; however, it uses Ethernet II for other traffic such as IP and MPLS. A typical Ethernet frame is shown in Figure 3.11 and consists of a set of bits organized into several fields. These fields include address fields, a variable size data field that carries from 46 to 1,500 bytes of data, and an error-checking field that checks the integrity of the bits in the frame to make sure that the frame has arrived intact. The original Ethernet standards defined the minimum frame size as 64 bytes and the maximum as 1,518 bytes. These numbers include all bytes from the destination MAC address field to the Frame Check Sequence (FCS) field. The preamble and the SFD fields are not included when quoting the size of a frame. The IEEE 802.3ac standard released in 1998 extended the maximum allowable frame size to 1,522 bytes to allow for a virtual LAN (VLAN) tag to be inserted into the Ethernet frame format (VLANs are discussed in 4). gigabit Ethernet and 10 gigabit Ethernet ports may support jumbo frames that can be 9,000 bytes.



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Photoelectrochemistry studies the effects occurring in electrochemical systems under the influence of light in the visible through ultraviolet region. Light quanta supply an extra energy to the system, hence the electrochemical reactions, which are thermodynamically or kinetically suppressed in the dark, may proceed at a high rate under illumination. (There also exists an opposite effect, where the (dark) electrochemical reactions lead to highly energetic products which are able to emit electromagnetic radiation. This is the principle of 'electrochemically generated luminescence', mentioned in Section 5.5.6.) Two groups of photoelectrochemical effects are traditionally distinguished: photogalvanic and photovoltaic. The photogalvanic effect is based on light absorption by a suitable photoactive redox species (dye) in the electrolyte solution. The photoexcited dye subsequently reacts with an electron donor or acceptor process, taking place in the vicinity of an electrode, is linked to the electrode





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Preamble SFD DA SA Length P a y l o a d (46 to 1500 bytes) Frame check sequence (4 bytes) Payload: Internet layer Frame length or type information (2 bytes) Source MAC address (6 bytes) Destination MAC address (6bytes) Fixed sequence to alert the receiver (8 bytes)

391 reaction which restores the original form of the dye The cycle is terminated by a counterelectrode reaction in the non-illuminated compartment of the cell Both electrode reactions may (but need not) regenerate the reactants consumed at the opposite electrodes The photopotential and photocurrent appear essentially as a result of concentration gradients introduced by an asymmetric illumination of the photoactive electrolyte solution between two inert electrodes Therefore, any photogalvanic cell can, in principle, be considered as a concentration cell The photovoltaic effect is initiated by light absorption in the electrode material This is practically important only with semiconductor electrodes, where the photogenerated, excited electrons or holes may, under certain conditions, react with electrolyte redox systems The photoredox reaction at the illuminated semiconductor thus drives the complementary (dark) reaction at the counterelectrode, which again may (but need not) regenerate the reactant consumed at the photoelectrode.

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Preamble This is a stream of bits used to allow the transmitter and receiver to synchronize their communication The preamble is an alternating pattern of binary 56 ones and zeros The preamble is immediately followed by the Start of Frame Delimiter Start of Frame Delimiter This is always 10101011 and is used to indicate the beginning of the frame information Destination Address (DA) This is the MAC address of the machine receiving data Source Address (SA) This is the MAC address of the machine transmitting data Length/Type The payload length or type field, also known as Ethertype If the Ethernet frame is in the 8023 format, this field is interpreted as length If the Ethernet frame is in the Ethernet II or original DIx format, this field is interpreted as type, or Ethertype The numeric value in this field determines whether the frame is an 802.

The regenerative mode of operation is, according to the IUPAC recommendation, denoted as 'photovoltaic cell' and the second one as 'photoelectrolytic cell' Alternative classification and terms will be discussed below The term 'photovoltaic effect' is further used to denote nonelectrochemical photoprocesses in solid-state metal/semiconductor interfaces (Schottky barrier contacts) and semiconductor/semiconductor {pin) junctions Analogously, the term 'photogalvanic effect' is used more generally to denote any photoexcitation of the dc current in a material (eg in solid ferroelectrics) Although confusion is not usual, electrochemical reactions initiated by light absorption in electrolyte solutions should be termed 'electrochemical photogalvanic effect', and reactions at photoexcited semiconductor electodes 'electrochemical photovoltaic effect' The boundary between effects thus defined is, however, not sharp If, for instance, light is absorbed by a layer of a photoactive adsorbate attached to the semiconductor electrode, it is apparently difficult to identify the light-absorbing medium as a 'solution' or 'electrode material'.

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