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61 some of substances exhibit only one of the features required, whilst lacking others, and thus their placing in the acid or base group is not certain The concept of 'hard' and 'soft' acids and bases ('HSAB') should also be mentioned here This is not a new theory of acids and bases but represents a useful classification of Lewis acids and bases from the point of view of their reactivity, as introduced by R G Pearson Hard acids (HA) have low polarizability and small dimensions, higher oxidation numbers and the 'hardness' increases with increasing oxidation number; they bind bases primarily through ionic bonds Typical examples are H + , Na + , Hg 2+ , Ca 2+ , Sn2+, VO 2+ , VO 2 2+ , (CH3)2Sn2+, A1(CH3)3, I 7+ , I 5+ , Cl 7+ , CO2, R3C+, SO3.



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Seq.no. 122 (next seq.no. 123) Ack.no. 0 Wnd 8192 LEN = 0B Seq.no. 286 (next seq.no. 287) Ack.no. 123 Wnd 8760 LEN = 0B Seq.no. 123 (next seq.no. 123) Ack.no. 287 Wnd 8192 LEN = 0B Seq.no. 123 (next seq.no. 323) Ack.no. 287 Wnd 8192 LEN = 200B Ack.no. 323 Wnd 8560 Seq.no. 323 (next seq.no. 723) Ack.no. 287 Wnd 8192 LEN = 400B Ack.no. 723 Wnd 8160 Seq.no. 723 (next seq.no. 724) Ack.no. 287 Wnd 8192 LEN = 0B Seq.no. 287 (next seq.no. 287 + 1) Ack.no. 724 Wnd 8160 LEN = 0B Seq.no. 724 (next seq.no. 724) Ack.no. 288 Wnd 8192 LEN = 0B





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Soft acids (SA) are strongly polarizable, have low or zero oxidation numbers, the 'softness' decreases with increasing oxidation number and if groups with a large negative charge are also bonded to the central atom, then the 'softness' increases; they bind bases primarily through covalent bonds Typical examples are Cu + , Ag + , Hg + , Cs + , Pd 2+ , Cd2+, Hg 2+ , Tl 3+ , T1(CH3)3, BH3, I + , Br + , HO 2 + , I2, Br2, O, Cl, Br, I, metal atoms, metals in the solid phase Hard bases (HB) have low polarizability and strong Br0nsted basicity; in the V, VI and VII groups of the periodic table, the first atom is always the hardest and the hardness decreases with increasing atomic number in the group.

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Typical examples are H2O, OH~, F", O 2 ", CH3COO~, SO42~, Cl", CO32", NO 3 ", ROH, RCT, R2O, NH3, RNH2, N2H4 Soft bases (SB) are strongly polarizable and generally have low Br0nsted basicity Typical examples are R2S, RSH, RS", I~, R3P, CN", CO, QH4, C6H6, H , R Obviously, a number of substances cannot be classified exactly Borderline acids include Fe 2+ , Sb 3+ , Ir 3+ , B(CH3)3, SO2, NO + , R 3 C + and C6H5+ and borderline bases include C6H5NH2, N3~, Br~, NO 2 ", and SO2~ Simple laws govern the reactions of these substances: hard acids react preferentially with hard bases and soft acids with soft bases Mixing of 'unsymmetrical' complexes results in the reaction HA SB + SA HB-^ HA HB + SA SB (14.

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34) For example, the ether RO C^ (of the HB SA type) is split by hydrogen iodide (of the HA SB type) to yield ROH (the HB HA type) and I G^ (the SB SA type) It is obvious that the Lewis theory and the HSAB concept are very important for the description of the mechanisms of chemical reactions; however, for electrochemistry the Br0nsted theory is quite adequate 145 Correlation of the properties of electrolytes in various solvents.

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It has already been mentioned several times that the strength of acids and bases is expressed by their dissociation constants KA and KB. This is

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