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While the role of acid-base indicators in acidimetric titrations has been surpassed by more advanced, automatic, potentiometric methods various metallochromic indicators are still in use in complexometric analysis. Here we shall deal only with acid-base indicators. According to the early view of Ostwald, acid-base indicators are weak acids or bases, the undissociated form of which differs in colour from the ionic form. For example, the molecule of an indicator HI dissociates in water according to the equation HI + H2O = H 3 O + + I" (1.4.41) The equilibrium constant of this reaction in a dilute solution is fH3O+][I-] (1.4.42) [HI] whence [HI] showing the dependence of the ratio [I ]/[HI] on pH. pH = pKi + log (1.4.43)



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67 In a later conception due to Hantzsch, an indicator possesses two tautomeric forms differing in colour, and at least one form functions as an acid or base. If both tautomeric forms are capable of dissociation their ions also differ in colour. However, the ions and molecules of the same form show identical light absorption because such a small variation of the structure of a molecule as the dissociation of a proton cannot cause a large change in molecular property such as light absorption. For example, phenolphthalein does not absorb visible light in the acid and neutral region, but at pH > 8.2 one of its hydroxyl groups becomes ionized and, at the same time, a tautomeric change takes place: )H

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(1.4.44)

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is a chromophore which absorbs light radiation in the whole visible region of the spectrum except for the long wavelength range (red light). On absorption by the quinoid system the light energy is dissipated in the form of the energy of thermal movement of solvent molecules. However, in the case of fluorescence indicators this energy is converted to light of different wavelength which is recorded with a fluorescence spectrometer. In the case of only one form of the indicator undergoing the tautomeric change to a coloured form (this is the case of phenolphthalein anion) the equilibrium between the original form of the indicator anion and its tautomeric form is characterized by the tautomeric constant KT = | ^ | (1.4.45)

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where I" is the coloured (in the case of phenolphthalein the quinoid) form of the anion of the indicator. For K 1 [I-]=s (1.4.46) where s is the overall concentration of the indicator. Thus, when substituting for [HI] =5 [I~] into Eq. (1.4.41) an analogy of the HendersonHasselbalch equation (1.4.26) is obtained, which is the basis of the determination of pH by means of acid-base indicators.

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