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Figure 7.4 The TCP three-way handshake. Host A sends a SYN request with a starting sequence number, an acknowledgement number set to zero, and the SYN bit set. Host B acknowledges this by sending a response with its own sequence number, an acknowledgement number equal to Host A s sequence number plus 1, and the SYN and ACK bits set. Host A then responds with a new sequence number equal to its initial sequence number plus 1, an acknowledgement number equal to Host B s sequence number plus 1, and the ACK bit set. Once these three packets are exchanged, the handshake is complete and communication can begin.



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(1.4.14)

1. SYN (seq = A, ack = 0) 2. SYN/ACK (seq = B, ack = A + 1)

(simple consideration reveals that [H2A] = c(l - ax)y [HA"] = cax{\ - a2), [A2~] = ca1a2, [H3O+] = ca1 + cala2, where c = [H2A] + [HA"] + [A 2 "]). For a weak acid (K[> K2 1) and not too dilute solution (aly a2 1), the last pair of equations simplifies to yield K\ ~ ca\ and K2 cocxoc2y so that [H 3 O + ] = cocx + cocxa2 - (K[c)m + tf2 (1.4.15)

TCP 3. ACK (seq = A + 1, ack = B + 1)





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In most systems, K2< K\. Otherwise (e.g. the first two dissociation steps for ethylenediaminetetraacetic acid EDTA) the first hydrogen ion capable of dissociation is stabilized by the presence of the second one and can dissociate only when the second begins to dissociate. As a result both hydrogen ions dissociate in one step. As the second dissociation constant is often much smaller than the first, a2 ocx 1 and [H2S+] ~cocx = (K[c)m. Thus, the acid can be considered as monobasic with the dissociation constant K[. Solvolysis of base B + S~ with a dissociation constant (1.4.16)

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Figure 7.4 shows how a three-way handshake is performed. In a TCP session, data is not transmitted until the three-way handshake is successfully completed and the session is considered open. The opening TCP segments include the initial sequence numbers from both sides, and these sequence numbers increase throughout the TCP conversation. The MSS is also agreed on during the three-way handshake. After a session is established between the two hosts, data can be transferred until the session is interrupted or shut down. The data is sent in TCP segments, which are a combination of the data and a TCP header. There are three steps to establish the TCP session, (hence the term three-way handshake). These steps are: One endpoint (host A) sends a TCP segment with the SYn bit set in the header. This indicates that the host wishes to establish a TCP connection. note this means that if the SYn bit is set, it is always the beginning of a conversation; it should never be set otherwise. TCP also selects a 32-bit sequence number to use for the session. This number is included in the TCP header and is known as the Initial

is usually formulated as dissociation of the cation of the base HB + so that Eqs (1.4.8) and (1.4.9) apply for BH + = HA. Obviously, for a conjugated acid-base pair K'A(BH+)K{i = Ksu, or

7.2 T R A nSP O RT C On T RO L PRO TO C O L (TC P)

(1.4.18)

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