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Fig. 5.40 Cyclic voltammogram of a bright platinum electrode in 0.5 M H2SO4. Geometrical area of the electrode 1.25 x 10~3cm2, periodical triangular potential sweep (dE/dt = 30 V s"1), temperature 20 C, the solution was bubbled with argon. (By courtesy of J. Weber)

As with all computer systems, the Alcatel-Lucent 7750 SR and 7450 ESS series systems require a configuration or boot file that contains key information that is necessary for the



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then the picture changes quite markedly. The shape of the voltammetric curve is also affected strongly by the procedure of annealing the electrode prior to the experiment. There are also very marked differences between the first voltammetric curve and the curve obtained after repeated pulsing. All these features are typical for electrocatalytic phenomena. It was demonstrated by R. Parsons and H. Gerischer that the adsorption energy of the hydrogen atom determines not only the rate of the Volmer reaction (5.7.1) but also the relative rates of all three reactions (5.7.1) to (5.7.3). The relative rates of these three reactions decide over the mechanism of the overall process of evolution or ionization of hydrogen and decide between possible rate-determining steps at electrodes from different materials. The effect of adsorption on the electroreduction of hydrogen ions, i.e. the Volmer reaction, is strongly affected by the potential difference in the diffuse electrical layer (Eq. 5.3.20). In the presence of iodide ions, the overpotential at a mercury electrode decreases, although the adsorption of iodide is minimal in the potential region corresponding to hydrogen evolution. The adsorption of iodide





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Continuous AF lowers the fps count to approximately 0.7, but that is because the G11 is continually focusing on the subject in real time. In this mode, the focus frame is automatically set to Center.

system to function correctly The 7750 SR and 7450 ESS systems use a Boot Options File (BOF) to configure the system for operations during the power-on process Each new system is shipped with a Compact Flash (CF) card that contains the files required to start the system Each processor on an Alcatel-Lucent 7750 SR or 7450 ESS product can have three compact flashes: cf1, cf2, and cf3 The flash sizes can be 256M, 512M, 1G, and 2G Flash cf3 is typically where the system files are stored, and that is where the system looks for the files when initializing The cf1 and cf2 cards can be used to store debug and accounting logs The cf3 card contains the following directories and files located off of the root directory: bootldr This file contains the system bootstrap image bofcfg The bof.

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Fig. 5.41 A single-crystal sphere of platinum (magnification 100x). It is prepared from a Pt wire by annealing in an oxygen-hydrogen flame or by electric current and by subsequent etching. The sphere is then cut parallel to the face with a required Miller index to obtain a single-crystal electrode. (By courtesy of E. Budevski)

cfg file is user-configurable and contains information such as: Management port IP address Location of the image files (primary, secondary, and tertiary) Location of the configuration files (primary, secondary, and tertiary) TiMOS-mnYz This directory is named according to the major and minor software release, type of release, and version For example, if the software release is version 12 software release zero, the name would be TiMOS-12R0 On modular systems such as the Alcatel-Lucent 7750 SR-12 or the 7450 ESS-12, this directory contains two files, cpmtim and iomtim, for the SF/CPM and IOM cards, respectively On fixed form chassis such as the 7750 SR-1 that have an integrated fabric/control and I/O, there is only one file, named bothtim The cpmtim image file is the software that is used to run on the Service Router or the Ethernet Services Switch.

retards the electrode process at other electrodes with large hydrogen overpotentials, such as the lead electrode. Hydrogen is evolved from water molecules in alkaline media at mercury and some other electrodes. As the adsorption energy increases, the rate of the Volmer reaction can increase until equilibrium is attained and the rate of the process is determined by either the Tafel or the Heyrovsky reaction. However, it is more probable for kinetic reasons that the Tafel reaction will occur at electrodes that form a moderately strong bond with adsorbed hydrogen (e.g. at platinum electrodes, at least in some cases). Electrodes that adsorb hydrogen strongly such as tungsten electrodes, are in practice completely covered with adsorbed hydrogen over a wide range of electrode potentials.

It is this software that is created and is tagged with a release number This software contains all the features required to configure and run protocols on the Service Router/Ethernet Services Switch configcfg This file contains the default configuration file The default configuration file is very basic and provides just enough information to make the system operational You can create other configuration files and point the system to them using the bofcfg file The layout of the file system on the cf3 card is shown in Figure 211..

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