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What is crucial is to see how the fields of the upper IP and TCP layers are wrapped or encapsulated in the data of the lower layers Here, the IP and TCP headers are, from the perspective of the Ethernet protocol, simply bytes in its data payload Similarly, from an IP packet s perspective, TCP fields are simply bytes in its data payload This layering of headers mimics the layering of the OSI model that we have already discussed and helps you visualize what it means for a protocol stack to be layered Before we move on to Ethernet addressing, it is important to re-emphasize how Ethernet fits into the picture of the OSI model Ethernet resides at the data link layer, and this layer can be subdivided further into two sublayers already mentioned, the Logical Link Control (LLC) and the Media Access Control (MAC).

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S(S 0 )

These sublayers are shown in Figure 313 The LLC interfaces between the network interface layer and the higher L3 protocol and may provide additional functions such as flow control or retransmission The MAC layer is responsible for determining the physical source and destination addresses for a particular frame and for the synchronization of data transmission and error checking Additionally, at the physical layer, Ethernet transceivers use a link.

S*(S1)

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integrity test to continually monitor the data path for activity. The Ethernet II type of frame used for IP does not contain an LLC header and therefore does not provide any LLC functions. IP uses Ethernet II simply for the transmission of frames on a shared media. You can see in Figure 3.12 and the description that follows it that the upperlayer protocol is IP and the Ethernet frame header is using the type field, indicating the format is Ethernet II.

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394 bimolecular homogeneous reaction with a molecule acting as electron donor (D) or acceptor (A). In the first case, we speak about reductive quenching: S* + D ^ S ~ + D+ (5.10.3) and in the second case, about oxidative quenching: S*+A^S++A~ (5.10.4) Photoredox reactions involving excited singlet molecules, 5*(5X) are relatively rare owing to short lifetimes r0; one exception is the molecule of oxonine (oxygen analogue of thionine, see below) possessing relatively long singlet lifetime (2.4 ns) and also small quantum yield of a non-radiative Sl-^ 7i conversion (intersystem crossing), about 3 10~3. Oxonin, therefore, reacts photochemically, e.g. with Fe 2+ via the excited singlet state. Figure 5.57 demonstrates that the photoexcited molecule S* exhibits, in both spin states, a lower ionization potential (IP*) and a higher electron affinity (EA*) in comparison with that of the ground state 5 molecule (IP, EA). Consequently, the photoexcited molecule 5* is a better oxidizing as well as reducing agent than the ground state molecule, S. Neglecting the entropy and pressure changes, we can express the relative change of the standard redox potential of the S/S~ couple as follows: E0(S/S~) - E0(S*/S~) = -(AG - ^G*)|F - -ejF and analogously: E (S+/S) - E (S+/S*) - ejF (5.10.6) ex is the excitation energy of 5 (mostly of the first triplet state, S*{TX)). The actual changes of the redox potentials introduced by photoexcitation are dramatic (cf. Table 5.6). Thus, the photoexcited molecule S* is a powerful redox reactant to drive various unusual redox reactions in the electrolyte.

OSI Application Presentation Session LLC Interface to the L3 protocol MAC L2 addressing, data transfer, sync, error control, and data flow Transport Network Data link Physical Lower layers Upper layers

By speaking about the quality of light, I m not making a value judgment like good or bad. Quality of light refers to its properties of hard lighting and soft lighting to affect

Table 5.6 Properties of three typical photoredox-active molecules, bpy denotes 2,2' bipyridine, TMPP is tetra Nmethylpyridine porphyrin; Amax is the wavelength of the absorption maximum, e is the extinction coefficient at Amax, cpT is the quantum yield of the formation of the excited triplet state, r0 is its lifetime, and EQ are standard redox potentials Thionine*

As previously mentioned, Ethernet has its own addressing scheme. The requirements for an Ethernet address are far less than that used by IP, and as such, the addressing scheme is much simpler. An Ethernet MAC address is a 48-bit (6 bytes) hexadecimal number consisting of only two (2) parts, the Organization Unit Identifier (OUI), which identifies the card s manufacturer, and a vendor assigned number. Each portion of the MAC address is 3 bytes. A MAC address is usually displayed in dashed hexadecimal notation as shown in Figure 3.14.

(5.10.5)

The OUI number is assigned by the IEEE to vendors such as Alcatel-Lucent. A few examples are Alcatel-Lucent Canada 00-80-21 and 00-DO-F6, Alcatel-Lucent USA 00-17-CC, and Alcatel-Lucent Italia 00-20-60. A list of various vendors OUIs can be found at the IEEE website: http://standards.ieee.org/regauth/oui/ index.shtml. MAC addresses are used for delivering a frame from one device to another on an Ethernet network. The MAC address of each device on the network must be unique, and it is this uniqueness that allows an Ethernet frame to be delivered only to the station for which it is intended. In Figure 3.15, a station with the source address 00:e0:b1:88:0d:c0 is delivering a frame to station 00:14:22:c5:79:87.

452 14 1.0 0.6 -1.28 1.26 0.84 -0.86

00:14:22:c5:79:87

ZnTMPP+ 560 16 0.90 655 1.2 -0.6

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