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1.3.2 More rigorous Debye-Hiickel treatment of the activity coefficient A more rigorous approach requires integration of Eq. (1.3.13) not over the whole volume of the solution but over the effective volume after the volume of the central ion has been excluded, as this region is not accessible for the ionic atmosphere. Thus, integration is carried out from r = ay i.e. from the distance of closest approach, equal to the effective ion diameter, which is the smallest mean distance to which the centres of other ions can approach the central ion. This value varies for various electrolytes (Table 1.3). In this refined procedure the integration constant appearing in Eq. (1.3.13) attains the value kx = [zkel4ne{\ + KO)\ exp {KO) and the potential \pk = zke/4jt [r(l + Ka)]'1 exp [ic(a r)]. This expression can again be separated into the contribution of the isolated central ion ip k and the contribution of the ionic atmosphere tya. As a result of the principle of linear field superposition, these two quantities can be added algebraically. The contribution of the

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Fig. 1.8 Dependence of the mean activity coefficient y >c of NaCl on the square root of molar concentration c at 25 C. Circles are experimental points. Curve 1 was calculated according to the Debye-Hiickel limiting law (1.3.25), curve 2 according to the approximation aB = 1 (Eq. 1.3.32); curve 3 according to the Debye-Hiickel equation (1.3.31), fl = 325nm; curve 4 according to the BatesGuggenheim approximation (1.3.33); curve 5 according to the Bates-Guggenheim approximation + linear term 0.1 C; curve 6 according to Eq. (1.3.38) for a=0.4nm, C = 0.055 dm 5 -mor 1 ionic atmosphere is then given by the expressions -1 (1.3.26)

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If you compare the digital photography process with the ne-art paintings by the masters, you may come up with the analogy that the pixels are your canvas, the camera is your brush, and the light is your paint. Thought of in this way, you begin to understand the relationship between these elements to help you create great images. Light might seem like a nebulous force to wrap your brain around, but your understanding of it and your developing the ability to see light before making photographs will bene t your photography in profound ways. Professional photographers speak often about seeing the light or creating their own light by using ash or re ectors to match the scene in their mind s eye, regardless of the ambient light they come upon in any given situation. Light can be better understood if you break it down to its three main components as it relates to photography: color, quality or intensity, and direction. Let s explore each of these in detail to better comprehend light and its importance in making memorable, lasting images.

It uses data link layer addressing known as Media Access Control (MAC) addresses, and it provides the ability to send a data frame to all devices on the network simultaneously (broadcasting) So while many things have changes from the early days at xerox, some key concepts have remained the same In fact, even in the early days, Ethernet technology began to take hold of the industry The Institute of Electrical and Electronics Engineers (IEEE) started project 802,.

(1.3.27)

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a (nm)

7a. note the operational state of the new interfaces. The command output shows evidence of another requirement for physical links to be operationally Up. What is that extra requirement (one router s configuration was changed to demonstrate this requirement.) 8. Create the remaining inter-router interfaces for the CE and PE routers. 9. now that L3 connectivity between all routers is configured, recheck the state of the interfaces to verify that they are all operationally Up. You can verify the configuration you entered with the info command: It shows everything that has been newly configured or changed from the default settings.

4.1 Late afternoon on the banks of the Colorado River in Grand Canyon. The light s color, quality, and direction all play a part in this desert scene.

*B:PE1>config>router# info -------------------------------------#------------------------------------echo IP Configuration #------------------------------------interface loopbackTest address 140.10.0.11/32 loopback exit interface system address 140.10.0.1/32 exit interface toCE1 address 140.10.0.101/30 port 1/1/1 exit interface toPE2 address 140.10.0.97/30 port 1/1/2 exit -------------------------------------*B:PE1>config>router#

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