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361 only the reduction of H2O2, proceeding analogously as in the reduction of oxygen (curve 2). The anodic evolution of oxygen takes place at platinum and other noble metal electrodes at high overpotentials. The polarization curve obeys the Tafel equation in the potential range from 1.2 to 2.0 V with a b value between 0.10 and 0.13. Under these conditions, the rate-controlling process is probably the oxidation of hydroxide ions or water molecules on the surface of the electrode covered with surface oxide: OH(ads) + e or H 2 O(ads)^ OH(ads) + H + + e 2OH(ads)^ O(ads) + H2O or and, finally, 2O(ads)- O 2 (5.7.16) OH(ads)^ O(ads) + H + + e (5.7.12) (5.7.13)



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2. Turn the Control dial to select i-Contrast and press the Function/Set button. The last image taken or viewed is displayed. 3. Turn the Control dial to select the image and press the Function/Set button. This displays the i-Contrast screen where you choose Auto, Low, Medium, or High intelligent Contrast control. The camera shows you the effect on the image to help you make your selection. 4. Press the Function/Set button to apply the control. The camera asks you to Save a new image or Cancel. 5. Use the Control dial or press the left or right area of the 4-Wat Controller to select OK and continue to add i-Contrast control to other images or press the Menu button to display the last corrected image. Choose Yes or No. The Playback menu is again displayed. Press the Playback button to return to shooting.

This is followed by a fast reaction, either (5.7.14) (5.7.15)

(continued)

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At more positive potentials, processes occur that depend on the composition of the electrolyte, such as the formation of H2S2O8 and HSO5 in sulphuric acid solutions, while the CIO; radical is formed in perchloric acid solutions, decomposing to form C1O2 and O2. The formation of ozone has been observed at high current densities in solutions of rather concentrated acids. 5.7.2 Inhibition of electrode processes Electrode processes can be retarded (i.e. their overpotential is increased) by the adsorption of the components of the electrolysed solution, of the products of the actual electrode reaction and of other substances formed at the electrode. Figure 5.43 depicts the effect of the adsorption of methanol on the adsorption of hydrogen at a platinum electrode (see page 353). The integral of the anodic current over the range of potentials including both peaks of the adsorption of hydrogen, as well as the integral corresponding to the cathodic current, is equal to the charge Qm = FTm, where Tm is the maximal surface concentration of hydrogen atoms. When another substance is also adsorbed on the electrode (here, methanol), with a surface concentration that does not change during the potential pulse, this substance prevents adsorption of hydrogen at sites that it occupies. If the curve of the hydrogen peaks is integrated under these circumstances, a different Q'm value is obtained. If one molecule of adsorbate occupies one site for hydrogen adsorption, then the relative coverage of the electrode by

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Fig. 5.43 Influence of methanol adsorption on the hydrogen adsorption at a bright platinum electrode in 0.5 M H 2 SO 4 . This is the same electrode as in Fig. 5.40 polarized by a single potential sweep (dE/df = 30 V s 1 ) from E = 0.5V to E = 0.1V. Concentration of methanol (in mol dm~3 from bottom to top): 0, 10~4, 10~\ 10~2, 10~\ 5. Methanol was adsorbed at " = 0.5 V during 2min (the equilibrium coverage was achieved), t = 20 C. (By courtesy of J. Weber) the adsorbed substance is 0 =

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(5.7.17)

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