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*A:Router1# show log log-id 99 ================================================================== Event Log 99 ================================================================== Description : Default System Log Memory Log contents [size=500 next event=237 (not wrapped)] 236 2000/01/01 09:13:23.24 UTC MINOR: CHASSIS #2002 Base Mda 1/1 Class MDA Module : inserted 235 2000/01/01 09:13:23.24 UTC WARNING: SYSTEM #2009 Base CHASSIS Status of Card 1 changed administrative state: inService, operational state: inService 234 2000/01/01 09:13:10.56 UTC WARNING: SYSTEM #2006 Base CHASSIS tmnxCardTable: Slot 1 configuration modified 233 2000/01/01 09:13:10.55 UTC WARNING: SYSTEM #2007 Base PORT Pool on MDA 1/2 Modified managed object created [... Additional output omitted ...] *A:Router1#



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(10,11,. . ,). Intercalation of some guest species, such as alkali metals, can simply be performed via a chemical reaction of a gaseous reactant with graphite. Some other guest species (e.g. H2SO4, HC1O4 and other inorganic acids), however, do not react spontaneously with graphite, but the intercalation can be induced by an auxiliary oxidizing or reducing agent. The redox reaction promo ting intercalation can also be performed electrochemically; the advantage of electrochemical intercalation is not only the absence of any foreign chemical agent and the corresponding reaction by-products, but also a precise control of potential, charge and kinetics of the process. The electrochemical intercalation into graphite leads in the most simple case to binary compounds (graphite salts) according to the schematic equations: Cn + M + + e"-> M + C~ Cn + A - - e ^ C A (5.5.30) (5.5.31)





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================================================================= Card Summary ================================================================= Slot Provisioned Equipped Admin Operational Card-type Card-type State State ----------------------------------------------------------------1 iom2-20g up unprovisioned A sfm-400g sfm-400g up up/active B sfm-400g up down/standby ================================================================= *A:Router1#

In the first case, the graphite lattice is negatively charged and the electrolyte cations, M + (alkali metals, N R | , etc.) compensate this charge by being inserted between the graphene layers. In the second case, anions, A" (CIOJ, AsF^, BF4", etc.) are analogously inserted to compensate the positive charge of the graphite host. Reactions (5.5.30) and (5.5.31) proceed prevailingly during intercalation from solid or polymer electrolytes (cf. Section 2.6) or melts. When using common liquid electrolyte solutions, a co-insertion of solvent molecules (and/or intercalation of solvated ions) very often occurs. The usual products of electrochemical intercalation are therefore ternary compounds of a general composition: M+(Solv)>;Cor C(Solv) y A~

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The electrochemical intercalation of HSO4 anions together with H2SO4 was described by Thiele in 1934. The composition of the product of prolonged anodic oxidation of graphite in concentrated sulphuric acid is

Compare the output of the show card command with the output from the same command in Step 1. The IOM has successfully been removed from the configuration. 5. Reconfigure the IOM so that it is available for subsequent lab exercises. (Refer to Step 2.) 6. Have a look at the main log to see if anything has been recorded as a result of these last few configuration changes. Remember: The log files are an excellent source of debugging and troubleshooting information!

318 and it is the stage 1 intercalation compound. By a very rapid heating of this compound, the intercalate vaporizes and forces the graphene layers apart, like in an accordion. The product is called exfoliated graphite', it exhibits various peculiar properties, for example, up to hundred times smaller density than graphite. It is used, for example, in the preparation of graphite foils. The electrochemical intercalation/insertion has not only a preparative significance, but appears equally useful for charge storage devices, such as electrochemical power sources and capacitors. For this purpose, the co-insertion of solvent molecules is undesired, since it limits the accessible specific faradaic capacity. The electrochemical intercalation/insertion is not a special property of graphite. It is apparent also with many other host/guest pairs, provided that the host lattice is a thermodynamically or kinetically stable system of interconnected vacant lattice sites for transport and location of guest species. Particularly useful are host lattices of inorganic oxides and sulphides with layer or chain-type structures. Figure 5.30 presents an example of the cathodic insertion of Li+ into the TiS2 host lattice, which is practically important in lithium batteries. The concept of electrochemical intercalation/insertion of guest ions into the host material is further used in connection with redox processes in electronically conductive polymers (polyacetylene, polypyrrole, etc., see below). The product of the electrochemical insertion reaction should also be an electrical conductor. The latter condition is sometimes by-passed, in systems where the non-conducting host material (e.g. fluorographite) is finely mixed with a conductive binder. All the mentioned host materials (graphite, oxides, sulphides, polymers, fluorographite) are studied as prospective cathodic materials for Li batteries. From this point of view, fluorographite, (CF^)^ with J C ^ I , deserves

7. If your router has additional IOM cards and you want or need to use them for the exercises, you will need to repeat the configuration step for all additional IOM cards. 8. Repeat the preceding steps for each of the other routers.

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