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OSPF uses a sequence number to ensure that LSAs are not transmitted around the OSPF area indefinitely. It also uses an acknowledgement process to guarantee reliability of LSA transmission to neighboring routers. The algorithm used by the OSPF router to process received LSAs is as follows: 1. If the sequence number in the LSA is lower than the one in the database, the incoming link state information is discarded, and the receiving router will update the sending router with the corresponding information in its own database. note that this is because a higher sequence number means that the receiving router already has more current information than it is receiving from the transmitting router. 2. If the sequence number is the same, an acknowledgement is sent. The incoming link state information is then discarded because the receiving router already has this information in its database. 3. If the sequence number is higher, the new link state information is populated in the topological database, an acknowledgement is sent, and the link state information is forwarded to its neighbors using the flooding process previously described. note that in all cases the receiving router will either send an acknowledgement or, in the case of reception of a lower sequence number, will update the sending router with the more current LSA. OSPF ensures that the LSA flooding process is reliable through the use of this acknowledgement process. Figure 9.9 illustrates the flooding process for an LSA with sequence number 123.



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diffusion coefficient, of course, depends on the concentration of the indifferent electrolyte. A similar situation occurs in tracer diffusion. This type of diffusion occurs for different abundances of an isotope in a component of the electrolyte at various sites in the solution, although the overall concentration of the electrolyte is identical at all points. Since the labelled and the original ions have the same diffusion coefficient, diffusion of the individual isotopes proceeds without formation of the diffusion potential gradient, so that the diffusion can again be described by the simple form of Fick's law. Experimental methods for determining diffusion coefficients are described in the following section. The diffusion coefficients of the individual ions at infinite dilution can be calculated from the ionic conductivities by using Eqs (2.3.22), (2.4.2) and (2.4.3). The individual diffusion coefficients of the ions in the presence of an excess of indifferent electrolyte are usually found by electrochemical methods such as polarography or chronopotentiometry (see Section 5.4). Examples of diffusion coefficients determined in this way are listed in Table 2.4. Table 2.5 gives examples of the diffusion coefficients of various salts in aqueous solutions in dependence on the concentration.





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Figure 9.9 The LSA with sequence number 123 is flooded from router R2 throughout the OSPF network. Every router will receive the LSA update and acknowledge its receipt. If a router has a sequence number for the LSA that is higher than the one it receives, it will discard the LSA with sequence number 123 and update its adjacent router with the more current LSA.

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118 255 Methods of measurement of diffusion coefficients Both steady-state and non-steady-state methods are used in the determination of diffusion coefficients In the steady-state methods (dc/dt = 0) the flux J and the concentration gradient dc/Sx are measured directly and the diffusion coefficient D is calculated according to Fick's first law, often without assuming that D is constant In non-steady-state methods, all the parameters of diffusion flux change with position and time and thus equations resulting from integration of Fick's second law must be employed with various boundary conditions, depending on the experimental arrangement In integration, when necessary, a suitable form of the function D(x, t) must be assumed Usually the diffusion coefficient is assumed to be constant and thus the final integrated equations can be used only for small concentration ranges in which the change in the diffusion coefficient can be neglected A steady-state method.

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In the diaphragm method the diffusion process is restricted to a porous diaphragm (a glass frit with a pore size of about lOjUm, separating compartments 1 and 2 of volumes V1 and V2 (cf Eq (2518) The diaphragm is the actual diffusion space with an effective cross-section of pores A and an effective length / The compartments are filled with solutions of concentrations c and c2 at the start of the experiment, and are thoroughly stirred during the experiment After a short time the solutions penetrate into the pores of the diaphragm and the solution diffuses from 1 to 2 if c\>c\ In the steady state there is no accumulation of the solute in the pores of the diaphragm, ie the same amount of solute which leaves the compartment 1 in a certain time interval passes into the compartment 2.

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