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As previously discussed, the transport layer is Layer 4 of the Open Systems Interconnection (OSI) model. The transport layer is designed to provide end-to-end control and information transfer of data sent from upper-layer applications. The goal of the transport layer is to relieve the upper layers from the need to provide reliable data transfer over an unreliable network protocol (such as Internet Protocol (IP)). The transport layer is the first layer of the OSI model that is concerned with ensuring the accurate delivery of data from one host to another. In the TCP/IP stack, the Transmission Control Protocol (TCP) and the User Datagram Protocol (UDP) provide services very similar to the OSI transport protocols and are therefore often referred to as transport or Layer 4 protocols. Internet applications such as Web browsing and email transfer use the services of the transport protocols. If the application needs a high level of service, such as reliable data transfer and flow control, the application typically uses TCP for data transfer as it provides these capabilities. If an application needs a simpler service with less overhead, the application may use UDP and perform any additional checking of data delivery itself.



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4.9 Auto white balance (AWB), 3750K. Taken at ISO 100, f/5.6, 1/100 second with a 21.7mm lens setting.

Although most higher-level protocols use TCP or UDP, there are a few higher-level protocols that do not use either of them. For example, the Open Shortest Path First (OSPF) routing protocol uses IP datagrams directly and does not use a transport layer protocol at all.





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Fig. 5.63 Scheme of a photoelectrochemical cell with sensitized semiconductor anode interface to form the oxidized, S + (reduced, S ) ground-state form via the majority charge carrier injection into the conduction (valence) band of the n- (p-) type semiconductor electrode. Practically more important is the sensitization of the n-type semiconductor electrode (Fig. 5.63). The depicted scheme is virtually equivalent to that in Fig. 5.62; the only exception is that the 'hole' is not created in the valence band but formally in the sensitizer molecule. The charge injection from the sensitizer, S*, dissolved in the electrolyte solution, might formally be considered as a photogalvanic process. The S* molecules must be able to diffuse to the semiconductor surface during their lifetime, r 0 . Assuming the usual lifetime, T O ^ 1 0 ~ 6 to 10" 4 s and the diffusion coefficient, D of 10~ 5 cm 2 /s, the effective diffusion distance of S*, (5D (see Eq. 2.5.9) is very small: <5D = (jtDr)V2 56 nm (5.10.26)

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Let us assume that the electrolyte is illuminated through the semiconductor electrode as shown in Fig. 5.58 (this is, in principle, possible since the semiconductor is transparent for wavelengths X>hcleg at which the sensitizer absorbs the radiation). The relative intensity of radiation transmitted to the distance <5D is given by the Lambert-Beer law: log (/// 0 ) = -8cdD (5.10.27)

The transport layer protocols that are defined in the OSI model provide a wide range of services. TP0 (Transport Protocol 0) provides the lowest level of service, and TP4 (Transport Protocol 4) provides the highest level of service. The services provided by TP4 are very similar to those provided by TCP. Both TP4 and TCP are built to provide a reliable, connection-oriented, end-to-end transport service on top of an unreliable network service. The network service may lose packets, store packets, deliver packets in the wrong order, or even duplicate packets. Both protocols must be able to deal with the most severe problems (e.g., a subnetwork stores valid packets and sends them at a later date). Both TP4 and TCP have connect, transfer, and disconnect phases, and their principles of operation during these phases are also quite similar. An application such as email that needs to transfer data across the Internet will use the services of an Internet transport protocol. email uses TCP, because email needs a

where e is the extinction coefficient of S and c its concentration. The light-harvesting efficiency 0 L is defined as: <pL = (1 -1/I o ) = 1 10~ C 6 D

reliable data transfer service. The application data is first passed to the TCP services layer. The TCP layer then divides the application data into segments, if necessary (if, e.g., the amount of application data is larger than a single TCP segment can accommodate). each TCP segment contains a TCP header. The size of the segments is based on the maximum transmission unit (MTU) size of the Layer 2 networks that are expected to be used for the transfer. The TCP segments are then passed to the IP services layer, where they are delivered across the network as IP datagrams. This encapsulation process is shown in Figure 7.1.

(5.10.28)

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