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The checksum is updated whenever the packet header is modified by a router (eg, to decrement the TTL) Source Address 32-bit IP address of the original sender of the packet Destination Address 32-bit IP address of the final destination of the packet Options not normally used, but when used, the IP header length is greater than five 32-bit words to indicate the size of the options field There are many options, but in modern networks most of them are no longer used originally one of the most common was the strict source route or loose source route These options allowed for the sending station to specify to intermediate stations how the packet was to be routed modern routing protocols alleviate most of the need for these and other options.

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428 The quantity K^iB2+ is termed the selectivity coefficient for the determinand B ^ with respect to the interferent B 2 + Obviously, for a B l + (l) ^BT+,B2+ B2+(1)5 Eq (639) is converted to Eq (633), often expressed by stating that the potential of the ion-selective electrode depends on the logarithm of the activity of the determinand ion with Nernstian slope A similar dependence is obtained for the ion B 2 + when a B l + (l) K^i,B2+0B2+(1) Equation (6310) is termed the Nikolsky equation Among cations, potassium, acetylcholine, some cationic surfactants (where the ion-exchanger ion is the p-chlorotetraphenylborate or tetraphenylborate), calcium (long-chain alkyl esters of phosphoric acid as ion-exchanger ions), among anions, nitrate, perchlorate and tetrafluoroborate (long-chain tetraalkylammonium cations in the membrane), etc, are determined with this type of ion-selective electrodes.

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The padding field is used to make sure that the header ends on a 32-bit boundary in the event that options are used You should make sure that you become familiar with the fields of the IP header especially the TTL, protocol, and addressing fields and understand why.

Especially sensitive and selective potassium and some other ion-selective electrodes employ special complexing agents in their membranes, termed ionophores (discussed in detail on page 445) These substances, which often have cyclic structures, bind alkali metal ions and some other cations in complexes with widely varying stability constants The membrane of an ion-selective electrode contains the salt of the determined cation with a hydrophobic anion (usually tetraphenylborate) and excess ionophore, so that the cation is mostly bound in the complex in the membrane It can readily be demonstrated that the membrane potential obeys Eq (633) In the presence of interferents, the selectivity coefficient is given approximately by the ratio of the stability constants of the complexes of the two ions with the ionophore.

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An IPv4 (IP version 4) address is 32 bits long in binary format. It is normally expressed as four decimal numbers as a simpler representation for humans. Each decimal number is separated by a dot. This format is called dotted-decimal notation. The dotted-decimal format divides the 32-bit IP address into four octets of 8 bits each. These octets specify the value of each field as a decimal number, as shown in Figure 5.3. The range of each octet (byte) is from 0 to 255.

The PowerShot G11 gives you the option of shooting movies in two resolution settings, depending on your intended use. Choose the best setting for your video considering quality and portability and how you want to output it. 640. This is the largest size for video recorded with the PowerShot G11. At 640 x 480, it is similar in size to standard-de nition video and displays well on a regular television set. Although it s usually too large for e-mailing and can be uploaded only on the fastest Internet connections, if you are not sure where it s going to go, start with this size. You ll have recorded the video in the highest quality the G11 can produce and this footage can always be scaled down on a computer for e-mailing or Web usage later on. 320. The standard size for Internet usage is 320. With dimensions of 320 x 240, it is nearly half the image size of regular video but extends the shooting time almost three times longer. Considering the video s length, this resolution should be reduced for e-mailing purposes, but it s the most common size used for video-sharing sites such as YouTube. For comparison of video sizes, standard definition television is usually 720 x 486.

For the determination of potassium ions in the presence of interfering sodium ions, where the ionophore is the cyclic depsipeptide, valinomycin, the selectivity coefficient is A^ + Na+ ~ 10~4, so that this electrode can be used to determine potassium ions in the presence of a 104-fold excess of sodium ions 632 Ion -selective electrodes with fixed ion -exchanger sites This type of membrane consists of a water-insoluble solid or glassy electrolyte One ionic sort in this electrolyte is bound in the membrane structure, while the other, usually but not always the determinand ion, is mobile in the membrane (see Section 26) The theory of these ion-selective electrodes will be explained using the glass electrode as an example; this is the oldest and best known sensor in the whole field of ion-selective electrodes.

Figure 5.3 Routers represent IP addresses internally in binary format, while humans find it more convenient to use the decimal equivalent. Using the decimal version is fine, but there are operations that are performed on IP addresses that are best understood using binary.

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