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To accomplish this, the received data is buffered in a preset amount of buffer space until it is requested by the application The amount of buffer space is specified in the TCP header window-size parameter When the receiver sends an acknowledgement, the receiver s TCP header sets the value of the window-size parameter to specify the amount of buffer space (in bytes) that is available This is the maximum amount of data that the sender can send before it receives the next acknowledgement If the receiver s buffer becomes full, the receiver sends a window size of 0 and the sender cannot transmit any more data When the receiving application requests the data and the TCP buffer space is available, the receiver sends an updated window size and the sender can start to transmit more data.



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Thus, the buffering capacity depends on the composition of the buffer, i.e. on the concentration of the salt a or b. The maximum value found by differentiation of Eq. (1.4.27) with respect to a corresponds, for an acidic buffer, to b = \s. For practical purposes, a number of buffer mixtures have been proposed that are useful for various pH ranges. Procedures for their preparation and requirements on purity and definition of the chemicals used are given in laboratory manuals and tables. If the solvent is not protogenic but protophilic (acetone, dioxan, tetrahydrofuran, dimethylformamide, etc.), self-ionization obviously does not occur. Consequently, the dissolved acids are dissociated to a greater or lesser degree but dissolved bases do not undergo protolysis. Thus, there can exist only strong acids but no strong bases in these solvents. The pH is not defined for a solution that does not contain a dissolved acid (i.e. in the pure solvent or in the solution of a base). The pKA value can be defined but not





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6.9 By using a slow shutter speed and timing it just right, I was able to capture these palm trees during a city reworks celebration. Fireworks can also provide a one-of-a-kind backdrop for musicians and festival performers. Taken at ISO 400, f/8, 1.6 second with a 6.1mm lens setting.

The window value is always set by the receiver, which provides a flow control mechanism for the receiver Figure 76 illustrates an example of TCP flow control in which the receiver is receiving data faster than it can process it and therefore advertises a window size of 0 to halt the transfer of data from the sender The TCP flow control process works as follows: 1 The sender received an ACK from a previous transmission that indicates a window size of 5,000 bytes 2 The sender has 3,000 bytes to send and transmits them in three 1,000-byte segments, one after the other 3 The receiver buffers the received data and sends an ACK to acknowledge all the received data The receiver sets the window size to 2,000..

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58 the pKB value, and there is no neutral point. If the solvent is neither protogenic nor protophilic, then neither dissolved acids nor dissolved bases are protolysed. Protolytic reactions can occur in such a solvent, but only between dissolved acids and bases (that are not mutually conjugate). If the dielectric constant of an amphiprotic solvent is small, protolytic reactions are complicated by the formation of ion pairs. Acetic acid is often given as an example (denoted here as AcOH, with a relative dielectric constant of 6.2). In this solvent, a dissolved strong acid, perchloric acid, is completely dissociated but the ions produced partly form ion pairs, so that the concentration of solvated protons AcOH2+ and perchlorate anions is smaller than would correspond to a strong acid (their concentrations correspond to an acid with a pK'A of about 4.85). A weak acid in acetic acid medium, for example HC1, is even less dissociated than would correspond to its dissociation constant in the absence of ion-pair formation. The equilibrium HC1 + AcOH AcOH 2 + Cr * AcOH2+ + Cl" is established. If the constants

7.2 T R A nSP O RT C On T RO L PRO TO C O L (TC P)

(1.4.28)

Figure 7.6 The sender is transmitting data faster than the host can receive it. The first advertised window size is 5,000 in the first acknowledgment. After additional data is received, the receiver reduces its window size to 2,000 in the next acknowledgment. After still more data is received, the receiver reduces its window size to 0, effectively halting the sender from receiving any additional data until the receiver's buffer is cleared and it sends a non-zero window size to the sender. At this point, the sender can resume its transmission.

[AcOH 2 + Cr] [HC1] [AcOH2+Cl~] [AcOH 2 + ][Cr] [AcOH 2 + ][Cr] [HC1] + [AcOH 2 + Cr]

ACK number 27000, window = 5000 SEQ number 27000 SEQ number 28000 SEQ number 29000 1000 bytes data 1000 bytes data 1000 bytes data 3000 bytes buffered

Second-curtain sync, also known as Rear-curtain sync, allows the ash to re at the end of the exposure. When photographing moving subjects, if the ash res at the beginning of the exposure, the ambient light being recorded causes a blur in front of the subject, which can look unnatural. Using 2nd curtain sync causes the motion blur to lead up to or follow the subject. Second-curtain sync is most effective when using a long shutter speed and shooting against a dark background.

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