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Fortunately, the configuration process is very simple despite the large number of available MDAs. Objective In this exercise, you will become familiar with recognizing, identifying, and configuring MDAs from the CLI. Validation You will know you have succeeded if you can display the state of MDAs and if the MDAs show an operational state of Up. 1. Display and examine the current MDA configuration using the show mda command. Note that the exact output will depend entirely on your physical hardware.



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A great effort in this respect was triggered in 1975 when Miller et al attached the optically active methylester of phenylalanine by covalent bonding to a carbon electrode via the surface oxygen functionalities (cf Fig 527) Thus prepared, so-called 'chiral electrode' showed stereospecific reduction of 4-acetylpyridine and ethylphenylglyoxylate (but the product actually contained only a slight excess of one enantiomer) A large selection of chemical modifications employing the surface oxygen groups on carbon and other electrode materials (metals, semiconductors, oxides) has been presented For instance, surfaces with a high concentration of OH groups (typically SnO2 and other oxides) are modified by organosilanes: [S] OH + Cl SiR3- [S] O SiR3 (5532).

*A:Router1# show mda =================================================================== MDA Summary =================================================================== Slot Mda Provisioned Equipped Admin Operational Mda-type Mda-type State State ------------------------------------------------------------------1 1 m10-1gb-sfp-b up unprovisioned ===================================================================





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Selecting the proper light balance for shooting successful images takes time to learn, but I urge you to play with different settings and presets on the camera for creative effects. This next section, with gures 4.9 through 4.16, details what the same photograph looks like in the various preset white balance settings.

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320 where [S] stands for electrode surface, and the radical R might bear various electroactive species, such as ferrocene, viologenes, porphyrins, etc. Surfaces with OH groups can also be modified via l,3,5-trichloro-2,4,6-triazine as a coupling agent. This further reacts with alcohols, amines, Grignard reagents, etc. Another method employes the surface carboxylic groups on carbon electrodes, usually activated by conversion to acylchloride with SOC12, followed by esterification or amidization in order to anchor the desired electroactive species. In an ideal case the electroactive mediator is attached in a monolayer coverage to a flat surface. The immobilized redox couple shows a significantly different electrochemical behaviour in comparison with that transported to the electrode by diffusion from the electrolyte. For instance, the reversible charge transfer reaction of an immobilized mediator is characterized by a symmetrical cyclic voltammogram ( p c - E pa = 0; ypa = ~7pc= l/pl) depicted in Fig. 5.31. The peak current density, / p , is directly proportional to the potential sweep rate, v\ jp = n2F2Tv/ART (5.5.33)

1a. Important! Can you see any MDAs for IOMs that are not configured Repeat the steps from the previous exercise to remove the IOM configuration and repeat the command to see the available MDAs. 1b. In total, how many MDAs are physically plugged into an IOM(s) 1c. Which chassis slot/IOM is the m10-1gb-sfp-b MDA plugged into Within that IOM, is the MDA plugged into the first or second MDA slot 2. generally, an MDA will always be configured to be the same as shown in the Equipped Mda-type column. Configure the available MDA(s). Note that the exact command will depend entirely on your physical hardware; follow the rule of configuring the type the same as shown in the previous command.

where T is the surface coverage of electroactive species, which might simply be determined from the voltammetric charge per unit electrode area (area of the peak, see Fig. 5.31): T=Q/nF (5.5.34)

*A:Router1# configure card 1 mda 1 mda-type m10-1gb-sfp-b *A:Router1#

or, alternatively, by non-electrochemical techniques of surface analysis (Section 5.5.6). Besides the charge transfer reactions of the immobilized mediator, the

2a. What is the correspondence between the physical location of the MDA and the values specified in the above command 2b. Whether or not there was an asterisk in the prompt before issuing the configure command, will there be one after the command

Fig. 5.61 Current density-potential characteristics of n-semiconductor electrode in the dark and upon illumination

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