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routers operate at Layer 3 of the OSI model, and so an Ethernet frame would not be forwarded across a router. This boundary or domain that includes all of the Ethernet switches contained by a router boundary is known as a broadcast domain. It is important to understand that within a broadcast domain, every Ethernet device will receive and process all broadcast packets. In the event of a large number of broadcast packets, or broadcast storm, the processing at each station in the broadcast domain can be severely disrupted. This is one of many important functions of routers: They serve as broadcast packet boundaries. In contrast to a broadcast domain, a collision domain exists between devices only within a single wire or hub. A collision domain is a group of Ethernet or Fast Ethernet devices in a CSMA/CD LAN that are connected by repeaters or hubs and that compete for access in the network. Only one device in the collision domain may transmit at any one time, and the other devices in the domain listen to the network to avoid data collisions. A collision domain is sometimes referred to as an Ethernet segment. Devices on a hub are in a single collision domain, whereas each device on a switch has its own collision domain between the device and its individual port. Figure 4.5 illustrates these different domains.

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411 istry includes the more classical subjects of the thermodynamics and kinetics of redox processes of components of biological systems at electrodes This chapter will deal with the basic properties of electrochemical membranes in general and the membrane aspects of bioelectrochemistry in particular A number of bioelectrochemical topics was discussed in Sections 153 and 325 611 Classification of membranes In contrast to mechanics, where the term membrane (Lat membrana = parchment) designates an elastic, two-dimensional plate, this term is used in chemistry, biophysics and biology to designate a solid or liquid phase (usually, but not always, with a thickness substantially smaller than its other dimensions) separating two, usually liquid, phases The transport (permeation) of the various components of both phases through the membrane occurs at different rates relative to those in the homogeneous phases with which the membrane is in contact.

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Figure 1.9 shows the bottom features of the PowerShot G11, which includes the release latch and cover for the battery and memory card compartment, and the tripod socket used when securing the camera to a tripod or tripod quick-release plate.

Figure 4.5 Hubs provide no separation for collision or broadcast domains, switches provide collision domain separation, and routers provide both collision and broadcast domain separation.

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The membrane is consequently called semipermeable The thickness of the membrane phase can be either macroscopic ('thick') membranes with a thickness greater than micrometres or microscopic ('thin'), ie with thicknesses comparable to molecular dimensions (biological membranes and their models, bilayer lipid films) Thick membranes are crystalline, glassy or liquid, while thin membranes possess the properties of liquid crystals (fluid) or gels (crystalline) Depending on their structure, membranes can be separated into porous, where matter is transported through pores in the membrane, and compact, where the substance is transported either through the entire homogeneous membrane phase or its homogeneous parts Membranes can be homogeneous, where the whole membrane participates in the permeation of a substance, or heterogeneous, where the active component is anchored in a suitable support (for solid membranes) or absorbed in a suitable diaphragm or acts as a plasticizer in a polymeric film.

Figure 4.6 further illustrates the concepts of collision and broadcast domains. See if you can determine how many of each domain type exist in the figure (you can find the answer in the review section).

Both of the latter cases are connected with liquid membranes Biological membranes show heterogeneity at a molecular level Membranes exhibiting selectivity for ion permeation are termed electrochemical membranes These membranes must be distinguished from simple liquid junctions that are often formed in porous diaphragms (see Section 253) where they only prevent mixing of the two solutions by convection and have no effect on the mobility of the transported ions It will be seen in Sections 62 and 63 that the interior of some thick membranes has properties analogous to those of liquid junctions, but that the mobilities of the transported ions are changed 612 Membrane potentials A characteristic property of electrochemical membranes is the formation of an electric potential difference between the two sides of the membrane,.