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Figure 6.2 schematically depicts the concentration distribution in this ion-exchanger membrane. In the limiting case, Eq. (6.2.6) is converted to the relationships derived above: if the membrane is completely impermeable for the anion, then c_ p = c_ q = 0 and also IL = 0 and the membrane potential is given by the Nernst term (RT/F) In (cjc2) (cf. Eq. 6.1.3). If, on the other hand, the

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Both alternate and back-up ports remain in a discarding state unless there is a topology change that causes them to become the designated port. By keeping track of these additional ports, STP can allow a designated bridge to quickly transition its original root port to an alternative port in the event of a link or switch failure in the path to the root bridge. These enhancements are part of the rSTP changes made to STP in the 2004 release. In the next section, we leave the topics of STP and redundancy and wrap up this chapter with a discussion of virtual LANs.

Fig. 6.2 Concentration distribution of cations c+, anions c_ and fixed anions in a cationexchanging membrane. The bathing solutions have electrolyte concentrations cx and c2. (According to K. Sollner)

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A virtual LAN (VLAN) is a mechanism that allows you to segregate devices, and their associated traffic from other devices and traffic, even when all of the devices are physically part of the same switched infrastructure. The astute reader may immediately

419 membrane is completely permeable for both the cation and the anion, then cx = 0 as well as c+>q = c_ q = c2 and c+p = c_ p = cx and A0 M is given by the Henderson term alone, -(RT/F)(t+ -t_) In (cjc^ (cf. Eq. 2.5.31). 6.2.3 Transport through a fine-pore membrane

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wonder why you couldn t simply use a router to achieve this sort of separation. There is some merit to this question, as routers are the mechanisms that are typically used to segregate groups of Ethernet devices from one another. However, there are physical limitations on the deployment of routers, and those limitations may not match the physical locations for the deployment of devices in the same VLAN. For example, you might have devices in multiple buildings that are part of the same segregated group, and there might be a multiple of these types of groups in each building. Your goal would be to allow the devices in the segregated group to communicate with each other, but not with any other Ethernet devices. This would be difficult to accomplish using traditional network segregation with routers, but it is trivially easy with VLAN technology. There are two main reasons to use VLANs: To decrease the amount of broadcast traffic To increase the security of your network Let s first examine the reasons for decreasing the amount of broadcast traffic in your network. Broadcast traffic is increased in direct proportion to the number of stations in the LAN, as illustrated in Figure 4.14. Note that flat network means a network without routers or without VLANs or both.

Transport processes in ion-exchanger membranes are important in most applications. This section will first deal with interaction of the material flux through the membrane with the field of the diffuse double layer in its pores and also with mutual interaction of the fluxes of various thermodynamic quantities, treated by using the thermodynamics of irreversible processes (the phenomenological description of membrane processes in terms of the thermodynamics of irreversible processes is the principal application of this field in electrochemistry). First, for example, a cation-exchanger membrane will be considered, containing an excess of mobile cations (counterions) over anions (coions). On the transport of electric current, the cations give a greater electrical impulse to the solvent molecules than the anions, leading to formation of an electroosmotic flux in the direction of movement of the cations in the electric field. An electroosmotic flux is formed as a result of the effect of the electric field in the direction normal to the pores in the membrane, d<f>/dx, (assumed to be constant) on the charge in the electric diffuse layer in the pore with a charge density p. The charges move in the direction of the x axis (i.e. in the direction of the field), together with the whole solution with velocity v. At steady state

Figure 4.14 As broadcasts increase on a flat network, they quickly consume all available network resources.

_ r p = r/ (6.2.7) ax ay where r\ is the viscosity of the liquid in the pores. According to this equation the force acting on the charges is compensated by internal friction of the liquid. The coordinate in the direction perpendicular to the pore surface is denoted by y. The Poisson equation (Eq. 1.3.8) holds for the space charge (6.2.8)

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