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40 zero, so that the mean activity coefficient is given by the equation +2 h (1.3.41) n +2 Robinson and Stokes identified the quantity 0.4343 In y >JC with the expression on the left-hand side in Eq. (1.3.31). For the system considered here, m=nl/n0M0 (where Mo is the molar mass of the solvent, for water Mo = 0.018 kg/mol), so that In [(/i0 + 2 - h)/(n0 + 2)] = In [(1 + 2Mom - hMom)/(l + 2Mom)] and, according to Appendix A, y tX = y > w (l + 2Mom). Hence, log 7 , w = - 7 ^ ^ 7 7 - ^ / 2 log 0 - l o g [1 +(2-/z)M o m] As in view of Eq. (1.1.18) Ina0 = -(f>mMom and l (2-h)Mom (1.3.42) gives log y ,m = DH + 0A343[<t)mMoh + (2 - h)M0]m (1.3.42) Eq. (1.3.43) 2In y tX = 2In y' tX-h\nao-2\nn



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The Spanning Tree Protocol (STP) was developed to solve these instability and broadcast-storm issues. It was invented in 1985 by radia Perlman and was first published as a standard by the IEEE as 802.1D. revisions to STP were published in 1998 and 2004, and the rapid Spanning Tree Protocol (rSTP) was introduced in 1998 as IEEE 802.1w. In 2004, the IEEE incorporated the changes of rSTP into the Spanning Tree Protocol and obsoleted previous versions. This version was published as IEEE 802.1D-2004. Because the current version of STP incorporates all the advances of rSTP, for the remainder of this chapter, we will just use the term STP. You should keep in mind that our use of the acronym from this point forward refers to the current version of STP published in 2004 and not previous, obsolete versions. A few points about STP should be noted at the outset. First, STP is intended to prevent loops in an Ethernet switched network. It does this by selectively blocking ports





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where DH denotes the Debye-Hiickel term (1331) while the second term on the right-hand side corresponds to CI of Eq (1338) The Robinson-Stokes equation (1343) can be used to calculate the parameters a and h from the measured values of y m and 0 W In this way the hydration number can also be found, but only as the sum of the ion hydration numbers of all the ions in the electrolyte 'molecule' The appropriate calculations have been carried out for a number of systems (see Table 14) Equation (1343) describes the experimental data up to molalities of the order of units, so that it is formally very successful Ionic diameters vary from 035 to 062 nm.

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to achieve a loop-free topology. That is, it determines what ports it can put into a nonfunctioning state to prevent loops from occurring, while still allowing frames to reach every destination in the Ethernet network. Second, STP uses a root/branch/leaf model, which determines a single path to each leaf spanning the entire switched network. Finally, because end stations such as workstations or servers rarely act as Ethernet switches, they are usually not part of the STP protocol and do not participate in it. The first version of STP was slow at converging because of various issues with the protocol design. Many enhancements were introduced to improve convergence time with STP version IEEE 802.1d-2004, and the following discussion covers only the procedures in the current version. The exact mechanisms that STP uses to achieve a loopfree topology are the subject to which we now turn. You should keep in mind throughout this discussion that the sole purpose of STP is to build an active loop-free topology (active in the sense that the ports that are blocked can change in response to changed network conditions). In Figure 4.10, STP would create a loop-free topology out of the physically looped network by blocking the ports that connect Switches C and E. All of the processes that make up STP are used to accomplish this seemingly trivial goal. Spanning Tree topology can be thought of as a tree that includes the following components: A root (a root bridge/switch) Branches (LANs and designated bridges/switches) Leaves (end nodes)

The calculated hydration numbers for salts with a common anion retain the order expected for the cations of these salts (H + > Li + > Na + > K+ > Rb + ), but do not retain the order expected for the anions with a common cation (I~ > Br~ > Cl~) Furthermore, these numbers do not preserve additivity: for example /iNaci ~ ^KCI = 16, but /*Naci ~ hKl = 30 If it is assumed that chloride ions are practically not hydrated and the whole hydration number of chloride salts is attributed to the cation, then the numbers obtained are too large (eg 12 for CaCl2 and 137 for MgCl2).

Figure 4.10 STP will block the ports between Switches C and E, ensuring a loop-free topology in the switched network.

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