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when the diffusion potential inside of the membrane, A0 L (m) is neglected. With respect to Eq. (3.2.48), E=^ln^ (6 .3.3) F flBl+(2) As the concentration of the internal solution of the ion-selective electrode is constant, this type of electrode indicates the cation activity in the same way as a cation electrode (or as an anion electrode if the ion-exchanger ion is a hydrophobic cation). Consider that the test solution 1 contains an additional cation B 2 + that is identically or less hydrophilic than cation B ^ . Then the exchange reaction B ^ m ) + B 2 + (w) B 1 + (w) + B 2 + (m) occurs. The equilibrium constant of this reaction is (cf. page 63) (6.3.4)

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one of the main functions of the network layer is to get the data compiled by the source to its destination or set of destinations, regardless of where this destination physically exists, via logical, hierarchical addressing. The network layer can be considered as the lowest layer in the TCP/osI stack that is concerned with the end-to-end delivery of the application data. In this context, end-to-end means that IP is the first layer that can deliver information from any IP-capable device to any other IP-capable device, regardless of the underlying Layer 2 technologies. As mentioned earlier, it would be very difficult for an Ethernet device to deliver information to a non-Ethernet capable device, but not so for IP. IP achieves this with the help of unique, logical addressing and with a standard set of protocols to aid in the dissemination of these addresses throughout the network and

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the forwarding of the data based on the addressing scheme. As previously mentioned, the network layer also functions to separate out various broadcast domains to prevent broadcasts from overwhelming your network. It does this by ensuring that a broadcast on one Ethernet network or VLAn is not forwarded to another unrelated network or VLAn. Put simply, Ethernet broadcasts are contained within an Ethernet segment and are not propagated up the protocol stack to the network or higher layers. Devices that prevent these broadcasts from propagating from one Ethernet segment to another and use Layer 3 (L3) logical addressing to move data across a network are called routers. routers inspect the L3 information, consult an L3 address forwarding table, and then forward data out through the right interface based on the forwarding table. The L3 addressing is a logical address that can be changed depending on the addressing plan. It is unlike a physical address (Ethernet mAC address) that is permanently programmed in the firmware. An L3 address is unique and is used to identify all devices on the Internet. The addressing is based on a centralized plan, and the address distribution is controlled by a global authority known as the Internet Assigned Numbers Authority (IAnA). The reason for this control of addresses is to ensure that every Internet device has a unique address. This unique addressing ensures that data is delivered properly from a source to its correct destination no matter where in the world the devices are located.

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Note that there are exceptions to the concept of unique addressing, which will be discussed in later chapters.

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In order to properly forward packets based on L3 addressing, routers need a way to build a forwarding table of these addresses, just as Ethernet switches had to build a FDB table of L2 addresses. With routers this is accomplished through the use of a routing protocol that allows a router to automatically build up entries in the forwarding table for L3 addressing. routers consult this table when receiving an L3 packet to decide which physical interface to send this data out of. In addition to unique addressing and data forwarding, the network layer can get involved in marking the datagram specific to the application. This is to ensure differential treatment on the outbound packet by intermediate routers. This marking is what allows for different types of network traffic to be prioritized and forwarded differentially by intermediate routers and is a key component of quality of service (Qos) offerings by providers.

Fig. 5.31 Cyclic voltammogram of a chemically modified electrode with a monolayer of a reversible mediator. The shaded area corresponds to the charge Q

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