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containing an unpaired electron. The properties of the ESR signal of this substance yield information on its motion and location in the membrane. Liposomes also have a number of practical applications and can be used, for example, to introduce various Pharmaceuticals into the organism and even for the transfer of plasmids from one cell to another. 6.4.4 Membrane transport Passive transport. Similar to the lipid model, the non-polar interior of a biological membrane represents a barrier to the transport of hydrophilic substances; this is a very important function in preventing unwelcome substances from entering the cell and essential substances from leaving the cell. This property is demonstrated on a BLM which is almost impermeable for hydrophilic substances. Polar non-electrolytes that are hydrated in the aqueous solution can pass through the membrane, with a high activation energy for this process, 60-80 kJ mol"1. This activation is primarily a result of the large value of the Gibbs energy of transfer, i.e. the difference in solvation energy for the substance during transfer from the aqueous phase into the non-polar interior of the membrane. In contrast, hydrophobic molecules and ions pass quite readily through the cell or model membrane. This phenomenon is typical for hydrophobic

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by an IP address in the multicast range of 239.0.0.0 239.255.255.255 that defines membership in that particular group. An example is broadcast TV service. When a host wants to receive traffic for a certain channel, it uses a group membership protocol for that channel identified by a multicast range address 239.1.1.1, for instance. multicast routing protocols route traffic from its source to the various hosts that require the traffic. Figure 5.9 illustrates how multicast packets can be forwarded to various hosts throughout the network that are members of a particular multicast group.

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ions such as tetraphenylborate, dipicrylaminate, triiodide and tetraalkylammonium ions with long alkyl chains, etc. The transfer of hydrophobic ions through a BLM with applied external voltage consists of three steps: (a) Adsorption of the ion on the BLM (b) Transfer across the energy barrier within the BLM (c) Desorption from the other side of the BLM As the membrane has a surface charge leading to formation of a diffuse electrical layer, the adsorption of ions on the BLM is affected by the potential difference in the diffuse layer on both outer sides of the membrane 02 (the term surface potential is often used for this value in biophysics). Figure 6.12 depicts the distribution of the electric potential in the membrane and its vicinity. It will be assumed that the concentration c of the transferred univalent cation is identical on both sides of the membrane and that adsorption obeys a linear isotherm. Its velocity on the p side of the membrane (see scheme 6.1.1) is then

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Figure 5.9 Routers and switches can listen for multicast updates and build forwarding tables based on this information. In this way, multicasts can be forwarded to only those network segments and hosts that are members of a multicast group. In the figure, only Hosts 1, 6, and 3 will receive the multicast packets from the source.

r( P ) + r(q)

A final type of IP address is an anycast. An anycast address is created simply: You assign the same unicast address to two or more hosts. In theory, such hosts are functionally equivalent, and you would want to route packets to the nearest host. This works well in applications such as distributed websites. With the aid of dynamic routing protocols, the packets can find the nearest host, and in case that host is not available, traffic will be routed to the next nearest host.

(6.4.1)

5.5 Although the PowerShot G11 accepts several different types of memory cards, SD (Secure Data) and SDHC (Secure Digital High Capacity) cards shown here are the most popular.

now that we have covered the basics of IP addressing, it s time to examine how a given IP address can be broken down into smaller networks From the discussion so far, you have seen that the original classful addressing specified which part of the IP address was the network and which part was the host For example, using classful addressing, the address 17216201 means network 17216 and host 201 (172 is between 128 and 191) This means that you could have up to 65,536 hosts (216) on this network However, what if you needed more networks, and fewer hosts per network After all, it is not typical to need 65k hosts on one network This is where the concept of subnetting comes in subnetting allows you to create additional subnetworks from a single network, with each subnet providing for fewer hosts.

where F(p) and F(q) are the surface concentrations of the adsorbed ion on the membrane surfaces, /ca and kd are the rates of adsorption and desorption, respectively, cs is the volume concentration of the ion at the surface of the membrane given by Eq. (4.3.5) and k and k are the rate constants for ion transfer. This process can be described by using the relationship of electrochemical kinetics (5.2.24) for a = \\