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93 the molar conductivity of strong electrolytes on the concentration. It can be seen that even at rather low concentrations, the limiting molar conductivity is still not attained. A special branch of the theory of strong electrolytes deals with the dependence of the electrical conductivity of electrolytes on concentration (see Section 2.4.3). For very low concentrations, Kohlrausch found empirically that A = A -Ax 1/2 (2.4.15)



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*A:PE2# show router route-table =============================================================== Route Table (Router: Base) =============================================================== Dest Prefix Type Proto Age Pref Next Hop[Interface Name] Metric --------------------------------------------------------------140.10.0.0/24 Remote Static 00h58m13s 5 140.10.0.97 1 140.10.0.96/30 Local Local 02d20h51m 0 toPE1 0 150.10.0.1/32 Local Local 02d21h20m 0 system 0 150.10.0.11/32 Local Local 02d21h19m 0 loopbackTest 0 --------------------------------------------------------------No. of Routes: 4 =============================================================== *A:PE2# *A:CE1# show router route-table =============================================================== Route Table (Router: Base) =============================================================== Dest Prefix Type Proto Age Pref Next Hop[Interface Name] Metric --------------------------------------------------------------0.0.0.0/0 Remote Static 00h01m48s 5 140.10.0.101 1 140.10.0.3/32 Local Local 02d21h20m 0 system 0 140.10.0.12/32 Local Local 02d21h21m 0 loopbackTest 0 140.10.0.100/30 Local Local 02d21h19m 0 toPE1 0 --------------------------------------------------------------No. of Routes: 4 =============================================================== *A:CE1#





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(k is an empirical constant), i.e. the dependence of A on cm is linear. Interionic forces are relatively less important for weak electrolytes because the concentrations of ions are relatively rather low as a result of incomplete dissociation. Thus, in agreement with the classical (Arrhenius) theory of weak electrolytes, the concentration dependence of the molar conductivity can be attributed approximately to the dependence of the degree of dissociation a on the concentration. If the degree of dissociation ~^ (2.4.16)

6a. Can you account for each of the routes in each router s routing table 7. Verify the proper operation of the routes by pinging between each pair of adjacent routers. If any ping fails, confirm that there are no mistakes in any route type, subnet/mask, or next-hop values. 8. Use ping and traceroute between CE1 and PE2. Confirm that each router can reach the other s system and loopback interfaces. 8a. How is it possible for CE1 to reach PE2 when there is no route for the 150.10.0.0/24 subnet in CE1 s routing table 8b. How is it possible for PE2 to reach CE1 when there is no specific route to CE1 interfaces in PE2 s routing table 9. Using ping (and, optionally, traceroute), confirm that every router can reach every configured interface on every other router. 10. (Optional) Use traceroute to verify that PE2 can reach CE1. Use traceroute again to attempt connectivity with one of the aggregate customer IPs on CE1 and notice the difference in the output.

sometimes called the Ostwald dilution law. In a suitably linearized form, this equation can be used to calculate the quantities K' and A0 from measured values of A and c. However, the resulting values of K' are not thermodynamic dissociation constants; the latter can be found from conductivity measurements by a more complicated procedure (see Section 2.4.5). Figure 2.5 illustrates, as an example, the dependence of the molar conductivity on the concentration for acetic acid compared with hydrochloric acid. While the molar conductivity of strong electrolytes A0 can be measured directly, for determination of the ionic conductivities the measurable transport numbers must be used (cf. Eq. (2.4.12)). Table 2.1 lists the values of the limiting conductivities of some ions in aqueous solutions. 2.4.3 Interionic forces and conductivity The influence of interionic fores on ion mobilities is twofold. The electrophoretic effect (occurring also in the case of the electrophoretic motion of charged colloidal particles in an electric field, cf. p. 242) is caused by the simultaneous movement of the ion in the direction of the applied

*A:PE2# traceroute 140.10.0.3 traceroute to 140.10.0.3, 30 hops max, 40 byte packets 1 140.10.0.97 (140.10.0.97) <10 ms <10 ms <10 ms 2 140.10.0.3 (140.10.0.3) <10 ms <10 ms <10 ms *A:PE2# *A:PE2# traceroute 140.10.0.193 traceroute to 140.10.0.193, 30 hops max, 40 byte packets 1 140.10.0.97 (140.10.0.97) <10 ms !N <10 ms !N <10 ms !N *A:PE2#

Fig. 2.5 Dependence of the molar conductivity of the strong electrolyte (HCl) and of the weak electrolyte (CH3COOH) on the square root of concentration

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