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between vacant sites along crystalline regions in the polymer has only marginal significance for ion transport. The main arguments are: (1) completely amorphous polymers are also conducting, usually even better than the crystalline ones, and (ii) not only cations, but also anions are the mobile species in ion-solvating polymers. (For instance, the Li+ transport number in the PEO-LiClO4 complex is in the region of only 0.2-0.35, and drops, moreover, with increasing Li/PEO ratio.) The preconception of an immobile polymer host skeleton is also far from reality, especially for amorphous polymers. The transition between crystalline and amorphous polymers is characterized by the so-called glass transition temperature, Tg. This important quantity is defined as the temperature above which the polymer chains have acquired sufficient thermal energy for rotational or torsional oscillations to occur about the majority of bonds in the chain. Below Tg, the polymer chain has a more or less fixed conformation. On heating through the temperature Tg, there is an abrupt change of the coefficient of thermal expansion (or), compressibility, specific heat, diffusion coefficient, solubility of gases, refractive index, and many other properties including the chemical reactivity. In polymer electrolytes (even prevailingly crystalline), most of ions are transported via the mobile amorphous regions. The ion conduction should therefore be related to viscoelastic properties of the polymeric host and described by models analogous to that for ion transport in liquids. These include either the 'free volume model' or the 'configurational entropy model'. The former is based on the assumption that thermal fluctuations of the polymer skeleton open occasionally 'free volumes' into which the ionic (or other) species can migrate. For classical liquid electrolytes, the free volume per molecule, uf, is defined as:



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Assuming that your requirements are such that you require BGP, it is important to understand how BGP actually operates to build routing tables. It is to this topic that we now turn.

(2.6.15)

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neighbor relationships in BGP are somewhat different from what is normal in the IGP world. Traditionally, neighbors are always directly connected routers. With BGP, this is not the case. neighbors may be directly connected, but it is not required because BGP uses unicast TCP/IP for neighbor establishment. neighbor relationships can be established with any IP-reachable device properly configured as a BGP speaker. At the application layer, BGP functions similarly to other TCP/IP applications, such as Telnet, FTP, and HTTP. BGP may be viewed as an application because it uses registered port number 179 in the TCP/IP model. Figure 10.5 illustrates establishment of a BGP session.

where v is the average volume per molecule in the liquid and v0 is the van der Waals' volume of the molecule. For polymers, the free volume, uf, can

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Figure 10.5 BGP peer establishment functions much like other protocols that use TCP. Both BGP peers initiate TCP connections to create the session. Once a session is established, OPEN messages are exchanged, and then one of the TCP sessions is removed. Once the peers have exchanged keep-alive messages, the session is established and they can exchange updates. Afterward, keep-alive messages are exchanged and update messages sent when there is a network change.

130 also be expressed as: vf=vg[k + a(T-TJ] (2.6.16)

Router A Initiate TCP connection TCP Phase Initiate TCP connection OPEN BGP Session (AS Num) BGP Phase OPEN BGP Session (AS Num) Remove Redundant TCP connection Keep Alive Session Maintenance Keep Alive Router B

where vg is the volume per molecule at the glass transition temperature, Tg, a is the thermal expansion coefficient of the polymer, and A is a : non-dimensional constant. The ion transport in the polymer is conditioned by the formation of sufficiently large voids in the polymeric skeleton. The probability of this process, p, decreases exponentially with the total-to-free volume ratio, v/v{: p=exp(-v/vf) Equations (2.6.16) and (2.6.17) can be rearranged to the form: p =exp[-B/(r-r0)] (2.6.18) (2.6.17)

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Once a BGP peer is established, the BGP speakers exchange UPDATE messages. The purpose of the UPDATE is to exchange network layer Reachability Information (nlRI) as it occurs in the network. The CIDR block or prefix is contained within this nlRI. Also included are the prefix length, full AS path to the destination, and the next hop (recall that the AS path and next hop are mandatory attributes). The origin, AS path, and next hop attributes we briefly touched on earlier in the chapter are also included in the nlRI. nlRI updates announce new reachability information to BGP speakers, and they also indicate when a destination should be withdrawn if it is no longer reachable.

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