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The G11 allows you to set an adjustment to any of the presets or custom white balances settings, which is referred to as white balance shift or manually adjusting the white balance. To set a white balance shift on the G11, follow these steps: 1. Turn your camera on and select Program AE, Shutter Priority, Aperture Priority, Manual, Movie, or Quick Shot mode. 2. Press the Function/Set button. White balance is the rst choice on the top left. 3. Use the left/right areas of the 4-Way Controller to select any of the presets or Custom 1 or 2 from the choices on the bottom of the LCD screen. 4. With the White Balance choice screen active, press the Display button to reveal the White Balance adjustment screen.



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where c is the velocity of light. The light-harvesting efficiency of an electrode covered with an adsorbed sensitizer can be expressed in the form similar to Eq. (5.10.28): <p L =l-10- a d s r > (5.10.31)

2a. With the port operationally Up, what new information is available 3. Multiple ports can be configured to a functional state, if done with a single command on one line.





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where ads is the extinction coefficient of adsorbed sensitizer, T is the surface concentration of the adsorbate (in mol/cm2 of the physical surface area) and r is the roughness factor of the electrode. The latter is defined as the ratio of physical to geometrical surface areas (polycrystalline materials, such as semiconducting oxides may achieve the r values of about 102-103). The extinction coefficient, eads, can be approximated by the usual extinction coefficient of the solution, e (in cm2/mol). For a typical monomolecular coverage, T 10"1() mol/cm2, an electrode roughness factor r = 1000 and an extinction coefficient e a d s = 107cm2/mol, the light-harvesting efficiency is, in comparison to the preceding case, very high, cpL = 90 per cent. Moreover, the adsorbed sensitizer is in intimate contact with the semiconductor surface, hence the conditions for charge injection from S* into the semiconductor are almost ideal (c^ >100 per cent). The most successful sensitizers so far tested are complexes of Ru(II) with various derivatives of 2,2' bipyridine, e.g. 2,2'-bipyridine 4,4'-dicarboxylic acid (L). The Ru(II)L3 complex is adsorbed from an aqueous solution of suitable pH value to oxidic semiconductors via electrostatic bonds between COO~ groups of the ligands and the positively charged (protonized) semiconductor surface. The sensitization of n-TiO2 by RuL3 was studied in detail by M. Gratzel et al. The photoelectrochemical reaction is initiated by an electron injection into the conduction band of TiO2: *Ru(II)L3-> Ru(III)L3 + ec-b(TiO2) (5.10.32)

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*A:Router1# configure port 1/1/[2..10] no shutdown *A:Router1# show port [... Additional output omitted ...] *A:Router1#

The standard redox potential of Ru(III)L 3 /Ru(II)L 3 equals 1.56 V( protonated form). Even energetically highly demanding processes, such as

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406 oxidation of water to oxygen (E{)= 1.229V) and bromide to Br2 (Eo = 1.0873 V) are thermodynamically possible. Two reactions deserve special attention, since they enable the construction of highly efficient regenerative cells 2Ru(III)U- + 21" -> 2Ru(II)U- 4-I2, 2Ru(III)U- + 2Br"-* 2Ru(II)L^" 4- Br2, IPCE (450 nm) - 70% IPCE (450 nm) - 55%

5. Don t forget to check the log files to see the corresponding entries for these operations. 6. Configure all ports Up that you need or want to use for the exercises. Remember to save your configuration. 7. Repeat the preceding steps for each of the other routers. 8. (Optional) Is it possible to shut down/remove an MDA while ports are still active Do the ports retain their previous state when the MDA is reconfigured Try it! (Don t worry, there s no risk of damaging the hardware.) 9. (Optional) If you have access to the physical hardware, try inserting and removing cables from a port and using a show port at each step to see the difference in the output.

5. Press the top, bottom, right, or left areas of the 4-Way Controller to adjust the white balance to your liking. The right and left controls change the amount of Blue or Amber that will be in a scene, while the top and bottom controls adjust the amounts of Green and Magenta. 6. Press the Menu button to change or reset the white balance to its original setting. When satis ed with your selections, press the Display button again to con rm your choices and return to shooting.

The best parameters of the I~/I2 cell were achieved by using a non-aqueous electrolyte and the anatase electrode of nanometer-sized particles, sensitized with Rul^ju - (NC)Ru(CN)(bpy)2)2. In 1991, B. O'Regan and M. Gratzel described a cell attaining parameters competitive to commercial, solid-state photovoltaic devices. 5.10.6 Photoelectrochemical solar energy conversion The solar spectrum corresponds roughly to the radiation of a black body at the temperature 5750 K. If we denote the photon flux in the wavelength interval from A to (A + dA) (in photons/m2 s) as /(A), the total solar power flux (in W/m2) is given as: Ps = hc\ /(A)dA (5.10.33)

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