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where Ksv = rokr is the so-called Stern-Volmer constant. Figure 5.58 presents a general scheme of photogalvanic cells based on reductive (a) or oxidative (b) quenching of 5*. These cells are regenerative if D and A are two forms of the same redox couple (D + = A and D =A~), otherwise the products D + and A~ accumulate in the electrolyte and the cell is photoelectrosynthetic. Some properties of three typical photoredox-active dyes are summarized in Table 5.6. The most important photogalvanic system is based on the photoredox reaction of thionine with Fe 2+ . It was first studied by E. Rabinowitch in 1940 and recently optimized by J. W. Albery et al. The structural formula of thionine, Thi+ and its reduction products (Sem+, Leu2+) are as follows:



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In this example, the frame is sent to a hub that connects all devices on a four-node LAN. The hub sends the frame out on all its ports except the port where the frame was received (the port attached to the source). All devices recognize that the destination address (ff:ff:ff:ff:ff:ff) is a special address and will process the frame. A broadcast message is actually a special case of the use of a multicast address, an address that is used by a group of nodes to receive messages intended just for that group. In this sense, the broadcast address is simply the special multicast group all nodes. There are special MAC address ranges that are reserved for multicast usage, and usage of these addresses typically requires additional configuration on a device via special software that makes use of the multicast functions. Figure 3.17 shows a device with source address 00:13:ce:2b:6b:28 sending to the multicast address 01:00:5e:01:01:01.





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The photoexcited thionone, *Thi + is reduced by Fe 2 + to the unstable semithionine (Sem + ) which further disproportionates to Thi + and the doubly reduced form of thionine, leucothionine (Leu 2 + ): (5.10.9) (5.10.10) The anodic reaction (taking place in the illuminated cell compartment) is a two-electron process regenerating the initial form of Thi + : Leu 2+ -* Thi+ + 2e" + 3H + (5.10.11) *Thi Fe 2Sem +

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Top. Top lighting is light that strikes the subject directly from above, such as on a sunny day at noon when the sun is directly overhead. While not entirely undesirable for some subjects, top lighting produces strong shadows in the eye sockets and under the chins of human subjects, and adds contrast. If the sky is clear, then strong, narrow shadows will appear, but if the sky is overcast, the clouds diffuse the top light and the effect is less harsh. Side. Perhaps the most attering lighting for a scene to show highlights and shadows along with texture and detail, side lighting or modi ed top/side lighting is light that strikes the subject from a lower angle and skims across the subject s features.

(a) (b) Fig. 5.58 Scheme of a photogalvanic cell. The homogeneous photoredox process takes place in the vicinity of the optically transparent anode (a) or cathode (b) The two-electron oxidation of the dye is not very common; other dyes usually undergo one-electron redox reactions. The cathodic reaction (taking place in the non-illuminated cell compartment) regenerates the complementary redox system: Fe 3+ + e"- Fe 2 + (5.10.12) According to the reactions (5.10.9)-(5.10.12), we can classify this cell as a regenerative (AG = 0) photogalvanic cell based on reductive quenching (Fig. 5.58a). Good performance of the iron-thionine cell is conditioned by the generation of *Thi+ (and Leu2+) in close vicinity (below ca. 1 jum) of the anode; this can be achieved by using an optically transparent (e.g. SnO2) anode as a window (Fig. 5.58). The selectivity of the anode and cathode for the desired reactions (5.9.24) and (5.9.25) may be further increased by selecting the proper electrode materials or by chemical modification of the anode. A regenerative photogalvanic cell with oxidative quenching (Fig. 5.58b) is based, for example, on the Fe 3+ -Ru(bpy)| + system. In contrast to the iron-thionine cell, the homogeneous photoredox process takes place near the (optically transparent) cathode. The photoexcited *Ru(bpy)l+ ion reduces Fe3+ and the formed Ru(bpy)3+ and Fe 2+ are converted at the opposite electrodes to the initial state. More complicated photogalvanic cells may employ two light absorbing systems: one in the cathodic process and the other in the anodic process. An

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