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which is beyond the practically available values. The surface modified electrodes may also be rapidly deactivated by the mediator desorption or decomposition as well as by adsorption of impurities from the electrolyte. Therefore, recent interest has been focused prevailingly on electrodes modified by a multilayer coverage, which can easily be achieved by using polymer films on electrodes. In this case, the mediated electron transfer to solution species can proceed inside the whole film (which actually behaves as a system with a homogeneous catalyst), and the necessary turnover rate is relatively lower than in a monolayer. A discussion of the charge transfer reaction on the polymer-modified electrode should consider not only the interaction of the mediator with the electrode and a solution species (as with chemically modified electrodes), but also the transport processes across the film. Let us assume that a solution species S reacts with the mediator Red/Ox couple as depicted in Fig. 5.32. Besides the simple charge transfer reaction with the mediator at the interface film/solution, we have also to include diffusion of species S in the polymer film (the diffusion coefficient D Sp , which is usually much lower than in solution), and also charge propagation via immobilized redox centres in the film. This can formally be described by a diffusion coefficient Dp which is dependent on the concentration of the redox sites and their mutual distance (cf. Eq. (2.6.33). The charge propagates in the film by electron hopping between the polymer Red/Ox couples. This is controlled by the electrode potential only in a close proximity of the electrode; in more distant sites, the charge transport is driven by a concentration gradient of reduced or oxidized mediators. The observed faradaic current density, j F , is a superposition of

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Figure 5.1 There are end-hosts on ATM that need to communicate with hosts on Ethernet over a POS backbone. This situation requires IP routers to transfer the information from one L2 network to another.

Fig. 5.32 Scheme of the reduction of a solution species Sox within the polymer film. Electron transfer is mediated by the immobilized redox active sites Red/Ox

The IP layer is required to direct the data from the source PC to the destination PC in any direction. The routers play an important role in forwarding information based on the IP layer. The physical switches, which are TDm/ATm/Pos or Ethernet-based, are only concerned with directing the user data to their nearest router. The routers inspect the IP information and direct the data out of the appropriate interface based on its IP address.

these two contributions: diffusion of S and electron hopping in the film:

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An example of how IP packets are forwarded may be useful at this point. The data composed on one of the PCs on the left in Figure 5.1 will have a source IP of 138.120.54.98 (we will explain the IP address later in this chapter) and a destination IP address of 160.16.20.1, the address of a host on the right in Figure 5.1. since the destination IP address is not part of the local IP network, when data is sent out of the PC, it is sent to the router attached directly to the Layer 2 (ATm) switch by means of standard Layer 2 (ATm) forwarding, which we have previously discussed. The router r1 then has to make a choice and send the data out of one of its directly connected interfaces to either router r2 or r3. r2 and r3, in turn, will have to forward the packet out of their respective interfaces to r4 and then on to the Ethernet network. For r1 to send the data out of the correct interface, it must have the knowledge to do so. This knowledge is created using routing protocols that run on all the routers involved to create the L3 forwarding table, also known as a routing table. In Figure 5.1, routers r1 r4 will run the same routing protocol. routing tables are constructed on every router using the routing protocols, and it is these tables that are referenced when the incoming data has to be forwarded out of the right interface. routing tables typically contain at a minimum the L3 network and the physical interface on the current router that is associated to the Layer 3 network. It is also common to have a next-hop entry for the network that lists the next router that will receive the packet.

jF/nF = DSp(ds/dx)0 - Dp(dr/djc)0

An L3 network address means an IP network address such as 138.120.54.0/24 as opposed to a host address such as 138.120.54.98. We will discuss this much more when we discuss IP address subnetting.

(5.5.36)

A sample routing table for r1 might have an entry like this:

(s and r are the concentrations of species S and Red/Ox sites, respectively). The solution of Eq. (5.5.36) may differ for various particular situations and boundary conditions, but we can phenomenologically describe the mediated charge transfer process in the polymer film by an effective heterogeneous rate constant kp and the concentration of S in solution, cs:

R1# show router route-table =============================================================================== Route Table (Router: Base) =============================================================================== Dest Prefix Type Proto Age Pref Next Hop[Interface Name] Metric ------------------------------------------------------------------------------160.16.20.0/24 Local Local 01d10h28m 0 POStoR4 0

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