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431 poorly sensitive for both hydrogen and potassium ions, has found a wide application At pH 11 its selectivity constant for potassium ions with respect to sodium ions is K^+^K+ = 36 x 10~3 The membranes of the other ion-selective electrodes can be either homogeneous (a single crystal, a pressed polycrystalline pellet) or heterogeneous, where the crystalline substance is incorporated in the matrix of a suitable polymer (eg silicon rubber or Teflon) The equation controlling the potential is analogous to Eq (639) Silver halide electrodes (with properties similar to electrodes of the second kind) are made of AgCl, AgBr and Agl These electrodes, containing also Ag2S, are used for the determination of Cl~, Br~, I~ and CN~ ions in various inorganic and biological materials The lanthanum fluoride electrode (discussed in Section 26) is used to determine F~ ions in neutral and acid media.

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3 is 10101000, calculated as: 8th bit from left to right = 0 20 = 0 1 = 0 7th bit from left to right = 0 21 = 0 2 = 0 6th bit from left to right = 0 22 = 0 4 = 0 5th bit from left to right = 1 23 = 1 8 = 8 4th bit from left to right = 0 24 = 0 16 = 0 3rd bit from left to right = 1 25 = 1 32 = 32 2nd bit from left to right = 0 26 = 0 64 = 0 1st bit from left to right = 1 27 = 1 128 = 128 Adding these numbers gives you 0 + 0 + 0 + 8 + 0 + 32 + 0 + 128 = 168.

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After the pH-glass electrode, this is the most important of this group of electrodes The silver sulphide electrode is the most reliable electrode of this kind and is used to determine S2~, Ag+ and Hg2+ ions Electrodes containing a mixture of divalent metal sulphides and Ag2S are used to determine Pb 2+ , Cu2+ and Cd2+ 633 Calibration of ion -selective electrodes It has been emphasized repeatedly that the individual activity coefficients cannot be measured experimentally However, these values are required for a number of purposes, eg for calibration of ion-selective electrodes Thus, a conventional scale of ionic activities must be defined on the basis of suitably selected standards In addition, this definition must be consistent with the definition of the conventional activity scale for the oxonium ion, ie the definition of the practical pH scale.

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For the next dotted decimal position, the number is 2; this is derived from the binary 00000010: 8th bit from left to right = 0 20 = 0 1 = 0 7th bit from left to right = 1 21 = 1 2 = 2 6th bit from left to right = 0 22 = 0 4 = 0 5th bit from left to right = 0 23 = 0 8 = 0 4th bit from left to right = 0 24 = 0 16 = 0 3rd bit from left to right = 0 25 = 0 32 = 0 2nd bit from left to right = 0 26 = 0 64 = 0 1st bit from left to right = 0 27 = 0 128 = 0 Adding these numbers gives you 0 + 2 + 0 + 0 + 0 + 0 + 0 + 0 = 2..

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