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You can set the white balance by choosing one of the nine preset options: AWB, Daylight, Cloudy, Tungsten, Fluorescent, Fluorescent H (daylight uorescent), Flash, Underwater, or by setting a custom white balance preset that is speci c to the scene. The G11 also offers you two custom color balance settings for you to create, use, and store until you change them again. White balance options give you a variety of ways to ensure color that accurately re ects the light in the scene. The next series of images shows the difference in white balance settings from a photo shoot with Canon Speedlites shot in RAW format and processed following the preset s Kelvin rating. Each photo represents a different white balance setting with color temperatures ranging from 2850K to 7500K. The lower the color temperature, the more blue appears in the image. The higher the color temperature, the more red and yellow appear in the image. Don t fall into the habit of always relying on the automatic white balance settings, especially in mixed light or other difficult lighting situations. Try some of the white balance presets along with AWB to see which ones you like best for that particular scene.



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*A:Router1# show mda =================================================================== MDA Summary =================================================================== Slot Mda Provisioned Equipped Admin Operational Mda-type Mda-type State State ------------------------------------------------------------------1 1 m10-1gb-sfp-b m10-1gb-sfp-b up up =================================================================== *A:Router1#

Fig. 5.62 Scheme of a photovoltaic cell with nsemiconductor photoanode the p-semiconductor electrode as a photocathode. The most common photovoltaic cells are based on the combination of a semiconductor photoanode and a metal cathode (Fig. 5.62). Cells with a metal anode and a semiconductor photocathode or with a semiconductor photoanode and a semiconductor photocathode have, however, also been described. The potential which controls the photoelectrochemical reaction is generally not the photopotential defined by Eqs (5.10.20) and (5.10.21) (except for the very special case where the values of * v, REDOX and the initial Fermi energy of the counterelectrode are equal). The energy which drives the photoelectrochemical reaction, R can be expressed, for example, for an n-semiconductor electrode as





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3a. Did the configuration command change the number of physical MDAs or the number of available MDAs 4. Have a look at the main log to see what has been recorded as a result of this configuration change. Here s one last reminder: The log files are an excellent source of debugging and troubleshooting information!

eR = eg -

5. As with IOMs, if it s ever necessary to remove an MDA, a two-step process ensures a clean shutdown.

- (sc - eF)

*A:Router1# configure card 1 mda 1 shutdown *A:Router1# configure card 1 no mda 1 *A:Router1# show mda =================================================================== MDA Summary =================================================================== Slot Mda Provisioned Equipped Admin Operational Mda-type Mda-type State State ------------------------------------------------------------------1 1 m10-1gb-sfp-b up unprovisioned =================================================================== *A:Router1#

As you can see, white balance affects not only the colors of the image but also the look and feel. AWB is great in a pinch and in many picture-taking situations, but it is only making an approximate estimation in a millisecond s notice. Free yourself from always shooting in automatic white balance and experiment with the different controls and presets.

(5.10.23)

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5a. Whether or not there was an asterisk in the prompt before issuing the configure command, will there be one after the command

This energy is consumed to overcome the overpotentials of the electrode reactions (rja, rjc), the IR drop in the external circuit and electrolyte, and it might partly be converted into the free energy, AG, of stable products (if any) of the endoergic electrochemical reaction: R = e(r a + c + IR) + AG/NA (5.10.24) The electrochemical cell can again be of the regenerative or electrosynthetic type, as with the photogalvanic cells described above. In the regenerative photovoltaic cell, the electron donor (D) and acceptor (A) (see Fig. 5.62) are two redox forms of one reversible redox couple, e.g. Fe(CN)2~/4~, I 2 /I", Br 2 /Br", S2~/Sx~, etc. the cell reaction is cyclic (AG = 0, cf. Eq. (5.10.24) since D+=A and D=A~). On the other hand, in the electrosynthetic cell, the half-cell reactions are irreversible and the products (D+ and A~) accumulate in the electrolyte. The most carefully studied reaction of this type is photoelectrolysis of water (D+ = O2 and y4~ = H2). Other photoelectrosynthetic studies include the preparation of S2OI , the reduction of CO2 to formic acid, N2 to NH3, etc. The photoelectroiysis of water was first studied in 1971 by A. Fujisima

6. Reconfigure the MDA so that it is available for subsequent lab exercises. 7. If your router has additional MDAs and you want or need to use them for the exercises, you will need to repeat the configuration step for all additional MDAs. Don t forget to save your configuration. 8. Repeat the preceding steps for each of the other routers.

and K Honda, who used a n-TiO2 photoanode and a Pt counterelectrode From the band positions and the formal energy levels of the H + /H 2 and O2/H2O couples (Fig 559), it is, nevertheless, apparent that the cell: n-TiO2 |aqueous electrolyte| Pt (51025) does not provide sufficient voltage for photoelectrolysis of water (1229 V) since the energy level of hydrogen electrode at pH 7 is about 02 V above the conduction band edge (this difference remains constant also at other pH values since both energy levels show the same Nernstian shift with pH) The missing voltage has, therefore, to be supplied either from an external source (photoassisted electrolysis of water) or by immersing the electrodes into electrolytes of different pH values (photoanode in alkaline and cathode in acidic electrolyte, the electrolytes being separated by a suitable membrane).

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