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with m in g s l and tx in s. The theory of voltammetry with rotating disk electrode (RDE) was described in Sections 2.7.2 and 5.4.1. The properties of the voltammetric ultramicroelectrode {UME) were discussed in Sections 2.5.1 and 5.5.1 (Fig. 5.19). The steady-state limiting diffusion current to a spherical UME is Id = 4jtnFDrQc0 while to a hemispherical UME placed on an insulating support Id = 2jtnFDroco (5.5.13) (5.5.12)



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*A:CE1>config>router# ping 140.10.0.101 PING 140.10.0.101 56 data bytes 64 bytes from 140.10.0.101: icmp_seq=1 ttl=64 time=10ms. 64 bytes from 140.10.0.101: icmp_seq=2 ttl=64 time<10ms. [... Additional output omitted ...] [ Output captured from PE1 terminal session ] 1 2000/01/01 13:53:45.62 UTC MINOR: DEBUG #2001 Base PIP PIP: ICMP instance 1 (Base), interface index 4 (toCE1), ICMP ingressing on toCE1: 140.10.0.102 -> 140.10.0.101 type: Echo (8) code: No Code (0) 2 2000/01/01 13:53:45.62 UTC MINOR: DEBUG #2001 Base PIP PIP: ICMP instance 1 (Base), interface index 4 (toCE1), ICMP egressing on toCE1: 140.10.0.101 -> 140.10.0.102 type: Echo Reply (0) code: No Code (0)

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3a. examine the output on Pe1 carefully. each ICMP packet is numbered in ascending order. Why are there 10 packets showing up on Pe1 when Ce1 only launched five ping requests 3b. Can you find where the ingress/egress interface is identified 4. Modify the ping command: The source IP address embedded in the ICMP echo request packet should be the system interface address.

Fig. 5.19 Electrodes used in voltammetry. A dropping mercury electrode (DME). R denotes the reservoir filled with mercury and connected by a plastic tube to the glass capillary at the tip of which the mercury drop is formed. B ultramicroelectrode (UME). The actual electrode is the microdisk at the tip of a Wollaston wire (a material often used for UME) sealed in the glass tube

*A:CE1# ping 140.10.0.101 source 140.10.0.3 PING 140.10.0.101 56 data bytes Request timed out. icmp_seq=1. Request timed out. icmp_seq=2. [... Additional output omitted ...]

299 For a disk UME situated in the plane of the insulating support Id = 4nFDroco (5.5.14)

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[ Output captured from PE1 terminal session ] 11 2000/01/01 14:04:50.33 UTC MINOR: DEBUG #2001 Base PIP PIP: ICMP instance 1 (Base), interface index 4 (toCE1), ICMP ingressing on toCE1: 140.10.0.3 -> 140.10.0.101 type: Echo (8) code: No Code (0) 12 2000/01/01 14:04:51.33 UTC MINOR: DEBUG #2001 Base PIP PIP: ICMP instance 1 (Base), interface index 4 (toCE1), ICMP ingressing on toCE1: 140.10.0.3 -> 140.10.0.101 type: Echo (8) code: No Code (0)

The non-steady state situation at UME represents a comparatively simple problem at a spherical electrode while it is very difficult to solve in the case of a disk electrode When comparing these three voltammetric electrodes they show different performance with respect to the purpose of their use 1 With a DME, clean surface is quite easy to achieve whereas with the other electrodes a special treatment of the surface is required in order to obtain reproducible results (page 307) Even in solutions containing surfactants, the amount adsorbed at DME can be controlled (cf Section 364) 2 The mass transfer coefficient for both RDE and UME can be varied in a large interval while in the case of DME it is much smaller and also the possibility of changing it is rather restricted 3.

4a. How many ICMP requests appear on Ce1 How many requests are successfully received by Pe1 How many replies are sent 4b. In which direction (ingress/egress) is all the traffic flowing under these circumstances Why 5. To verify ARP operation, turn on debug only for ARP on Pe1. Start with an empty ARP cache by executing the following commands on each of the routers, and then start a ping to Pe1 from either Ce1 or Pe2.

In contrast to DME, the charging of the electric double layer makes no problem with RDE and UME 4 The work with both DME and RDE requires the use of a base (supporting or indifferent) electrolyte, the concentration of which is at least twenty times higher than that of the electroactive species With UME it is possible to work even in the absence of a base electrolyte The ohmic potential difference represents no problem with UME while in the case of both other electrodes it must be accounted for in not sufficiently conductive media The situation is particularly difficult with DME Usually no potentiostat is needed for the work with UME 5 The area of the electrode can easily be measured with DME and RDE while in the case of very small UME it is often difficult to determine 6.

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