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Pros were attracted to their retro design and external controls, such as the exposure compensation, ISO, and shooting mode dials. The G-series continued to improve with the G2, G3, G5, G6, G7, G9, and G10. There were no G-series cameras with a 4 or 8 designation.



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393 5.10.3 Homogeneous photoredox reactions and photogalvanic effects The photogalvanic effects are initiated by a homogeneous photoredox reaction of an electrolyte redox system with a suitable photoexcited organic or organometallic substance (dye), S. The photon absorption produces a short-lived, electronically excited dye molecule, S*:

..CEa#..R.....E. .!....@....x5..x 5....U..l..{g.P. @..........devic e: sTW32fbi82.. ..Alcatel Networ ks Canada, 600 M arch Road, Kanat a, Ontario..Unau thorized access prohibited. Acc ess to this dev

whose structure and physicochemical properties are different. The conversion of 5* back to 5 proceeds by various radiative and non-radiative relaxation processes, which are characterized by a pseudo-first-order rate constant, kb. Its reciprocal value defines the lifetime of the excited state, r0: ro=l/kb (5.10.2)





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Ethernet II, Src FoundryN_d4:a5:00 (00:e0:52:d4:a5:00), Dst: Dell_45:61:23 (00:11:43:45:61:23) Destination: Dell_45:61:23 (00:11:43:45:61:23) Source: FoundryN_d4:a5:00 (00:e0:52:d4:a5:00) Type: IP (0x0800) Internet Protocol, Src 138.120.53.254 (138.120.53.254), Dst: 138.120.53.149 (138.120.53.149) Version: 4 Header length: 20 bytes Differentiated Services Field: 0x00 (DSCP 0x00: Default; ECN: 0x00) Total Length: 289 Identification: 0x0eab (3755) Flags: 0x00 Fragment offset: 0 Time to live: 64 Protocol: TCP (0x06) Header checksum: 0xeaa8 [correct]

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(the fraction of the S* molecules, deactivated during the time r 0 , equals 1 e~l 63%). Only excitations of electrons from the highest occupied molecular orbital (HOMO) to the lowest unoccupied molecular orbital (LUMO), which produce reasonably long-lived S* molecules are practically important. This is schematically depicted in Fig. 5.57. Most of the ground-state molecules contain all the electrons paired. (The 0 2 molecule is an important exception to this rule.) The excited molecule may occur in two states, either with none or two unpaired electrons; these states are called excited singlet, 5X, or excited triplet, Tx. The latter state is, according to the Pauli rule, energetically favoured and its lifetime is higher by orders of magnitude, since the reactions with singlet molecules as well as radiative relaxation (phosphorescence) are spin-forbidden. The photoexcited S*{TX) molecule may have a sufficiently long lifetime to diffuse some distance in the electrolyte solution and to take part in a

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Industry buzz on the G11 has been swift, and many believe this new PowerShot has retired, or at least stalled, the megapixel wars by dropping the pixel count on the G11 and including a faster processor to handle images. Canon reduced the megapixel resolution to 10 from 14.5 and kept the same lens as the G10. Canon says its new Dual Anti-Noise System combines a high sensitivity 10.0 megapixel image sensor with Canon s enhanced DiG!C 4 image processing technology to increase image quality and greatly improve noise performance by up to 2 stops (compared to the PowerShot G10). Further G11 improvements over the G10 include a higher 1/2000-second ash synchronization speed and an HDMI port for reviewing images on a high-de nition TV. The ash sync is impressive, especially when you consider that the PowerShot G11 is fully compatible with the 270EX, 430EX II, and 580EX II Speedlites plus the ST-E2 Speedlite transmitter. Even the MT-24EX macro twin-lite and MR-14EX macro ring-lite can be used for macro photography with the PowerShot G11.

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