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2a. upon (re-)booting, what time does a router show 2b. What are the settings for connecting to the router: via the serial port via the management Ethernet port 2c. In which file are the connection settings stored 2d. Which piece of hardware provides the serial number that is used for the default router name 3. On an uninitialized router, the time will always be incorrect. The next few steps are intended to show some of the excellent help features available through the CLI, so don t be afraid to experiment. Start typing the admin set-time command to set the time, but do not press the [Enter] key; type a question mark ( ) instead to get a complete list of available options.



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Sections 5.6.2 and 5.6.3 dealt with the deposition of metals from complexes; these processes follow the simple laws dealt with in Sections 5.2 and 5.3, particularly if they take place at mercury electrodes. The deposition of metals at solid electrodes (electrocrystallization) and their oxidation is connected with the kinetics of transformation of the solid phase, which has a specific character. A total of five different cases can be distinguished in these processes: 1. The deposition occurs at an electrode of a different metal or other conductive material (e.g. graphite). 2. The deposition occurs at an electrode of the same metal. 3. The metal is ionized in the anodic process to produce soluble ions. 4. The metal is anodically oxidized to ions that react with the components of the solution to yield an insoluble compound forming a surface film on the electrode. 5. A component of the solution participates in the anodic oxidation of the metal, so that the metal is converted directly into a surface film. These processes either lead to the formation of a new solid phase or the original solid phase grows or disappears. In addition to the electrochemical laws discussed earlier, this group of phenomena must be explained on the basis of the theory of new phase formation (crystallization, condensation, etc.). The basic properties of electrocrystallization can best be illustrated by the example of the deposition of a metal on an electrode of a different material (case 1).





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*A:Router1# admin set-time - set-time <date> <time> <date> <time> : YYYY/MM/DD : hh:mm[:ss]

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The formation of a new phase requires that the system be metastable, such as a supersaturated vapour prior to condensation, a supersaturated solution prior to crystallization, etc. The metastable situation of the system required for the formation of a new phase through an electrode reaction is brought about by the overpotential. At a suitable value of the excess energy in the system nuclei of the new phase are formed. If these nuclei are too small, then they become unstable as a result of the relatively high surface energy and decompose spontaneously. If their dimensions exceed a certain critical value, which is a function of the excess energy of the system, then they begin to grow spontaneously. Their formation requires a sufficiently large fluctuation of the variables of state of the system or the presence of sites at the interface at which nuclei can be formed with an overall decrease in the surface energy. The nucleation belongs to those processes where the individual events (of stochastic nature) occurring on the molecular level can be observed because of amplifying by subsequent macroscopic processes. Assume that current is passed either through the total nucleus surface area or through part thereof, such as the edge of a two-dimensional nucleus of monoatomic thickness. The transition of the ion M z+ to the metallic state obeys the equation for an irreversible electrode reaction, i.e. Eqs (5.2.12), (5.2.23) and (5.2.37). The effect of transport processes is neglected. The current density at time t thus depends on the number of nuclei and their active surface area. If there is a large number of nuclei, then the dependence of their number on time can be considered to be a continuous function. For the overall current density at time t we have -r)vndr (5.8.1)

notice that after displaying some help (the list of available options), the CLI re-typed your original command to leave you exactly where you were before typing the . 4. We all make mistakes from time to time. It s easy to interrupt or cancel at any time whatever has been typed: type [Ctrl]+C to kill everything that has been typed on the line.

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