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are introduced, then (1.4.30) The protolytic reaction between two molecules must be formulated as the formation of the pair B + HA^BH+A~ (1.4.31) that can react as a base with another acid HA,, or as an acid with another base B n : B,H + Ar + HA n <P* B,H + A,r + HA, BjH+Ar + B n ^ B u H + A r + Bj ' '

ACK number 30000, window = 2000 SEQ number 30000 1000 bytes data SEQ number 31000 1000 bytes data 5000 bytes buffered



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Protolytic reactions can also occur in fused salts. The solvent participates in these reactions provided that at least one of its ions has protogenic and/or protophilic character. An example of a solvent in which the cation is aprotic and the anion protophilic is ethylpyridinium bromide (m.p. 114 C). The acid HA is protolysed in this solvent (HA + B r ~ ^ H B r + A"). Hydrogen bromide acts as a solvated proton and the acidity is expressed as

ACK number 32000, window = 0 Application requests all data from TCP (5000 bytes) ACK number 32000, window = 5000 0 bytes buffered





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59 pHBr = log [HBr] and can be measured with a hydrogen electrode In ethylammonium chloride (mp 108 C) the cation is protogenic and selfionization occurs, C 2 H 5 NH 3 + + Cl~ <= C2H5NH2 +HC1, with the ion product 10"8'1 Fused alkali-metal hydroxides with amphiprotic OH~ anion are the most important of these solvents; the autoprotolysis follows the equation 2OH~~ ^H2O + O2~ Here, water is the strongest acid, corresponding to solvated protons, and O2~ is the strongest base Metal cations (added as hydroxides) behave as acids as they remove O2~ anions, forming compounds that often precipitate So far acid-base reactions of molecules in the ground state of energy have been discussed The properties of these molecules can change considerably in the electronically excited state (K Weber, T Forster, A Weller, et al).

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4. The sender has more data to send. Because the last window size was 2,000, the sender cannot send more than 2,000 bytes. This data is sent in two 1,000-byte segments. 5. The receiver buffers the 2,000 bytes as they are received. Because the application has not requested any data, the initial 3,000 bytes received are still being buffered. 6. The receiver s buffer is now full, and an ACK with a window value of 0 is sent. 7. even if the sender has more data to send, the sender must not transmit any more data because the window size is currently 0. 8. The application requests data from TCP, and the 5,000 bytes are taken from the buffer. The buffer is now empty, and an ACK is transmitted to re-set the window size to 5,000. 9. When the sender receives the new window size, the sender can now transmit more data.

For example, in aqueous solution in the ground state, 2-naphthol has pK'A = 95, while the value for the excited state is 25 Similarly for phenol, in the ground state, pK'A = 100, while the value for the excited state is 36 Thus, the strength of acids in these and a number of other cases increases by several orders on excitation Simultaneously, the pH of a solution calculated from the concentrations of species corresponding to the conjugate pair decreases by several pH units This effect is termed the laser pH jump' The effect is studied by irradiating the solution with a short intense pulse (usually provided by a laser hence the name) and fast fluorescence or absorption spectroscopy is employed to determine the concentrations of the corresponding excited acid species and the conjugated base.

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It is rare, given the CPU processing power of modern computers, for a TCP process to reduce its window size to zero in order to stop the data flow completely. What is more likely is for the window size to reduce slightly, as some segments are processed to slow down the sending host slightly, and then for the receiver to send an increased window size to allow the sender to begin transmitting more rapidly.

If the spectroscopy is sufficiently resolved in time (with resolution of the order of nanoseconds to picoseconds), the kinetics of the exchange of a proton between the dissolved conjugate pair and the solvent can be studied It has been found that this is a very fast reaction (with a rate constant of the order of 10 9 s- ! )144 Generalization of the concept of acids and bases.

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