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is obtained. The analysis of the power spectrum, the aim of which is, for example, to determine the characteristic constants of the processes from which the noise stems will not be discussed here and the reader is recommended to inspect the relevant papers listed on page 384. The electrocrystallization on an identical metal substrate is the slowest process of this type. Faster processes which are also much more frequent, are connected with ubiquitous defects in the crystal lattice, in particular with the screw dislocations (Fig. 5.25). As a result of the helical structure of the defect, a monoatomic step originates from the point where the new dislocation line intersects the surface of the crystal face. It can be seen in Fig. 5.48 that the wedge-shaped step gradually fills up during electrocrystallization; after completion it slowly moves across the crystal face and winds up into a spiral. The resultant progressive spiral cannot disappear from the crystal surface and thus provides a sufficient number of growth



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There would have to be a large number of IP stacks, or the IP stack code would be enormously large to account for all the separate devices it would need to interact with Any changes to the IP protocol would necessitate massive code changes for every conceivable type of hardware, and this seems very inefficient Enter the data link layer By having the data link layer interact with the hardware and provide its own local addressing, the IP stack can be written with minimal understanding of the physical hardware Indeed, Layer 3 protocols usually have no knowledge of the underlying physical infrastructure, nor do they need it, provided that the data link layer protocol is compatible with the Layer 3 protocol The data link layer hides the details of the interaction with the physical medium entirely from upper protocols such as IP.





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Fig. 5.49 A microphotograph of low pyramid formation during electrocrystallization of Ag on a single crystal Ag surface. (By courtesy of E. Budevski)

In theory, this would allow IP to run over any possible physical medium, provided there was an appropriate data link layer protocol that understood how to communicate with both the upper-layer protocol and the lower layer physical connection This has led to the mantra, IP Over Everything Of course, the astute reader may immediately recognize that in some ways, this explanation simply moves the problem down a layer If the data link layer must understand a wide variety of Layer 1 physical media, how is this necessarily better than.

3. Turn on the TV and switch it to play the HDMI input line the G11 is connected to. 4. Turn on the PowerShot G11 and press the Playback button. The G11 s LCD monitor will go dark and the images will be displayed on the high-de nition TV. Use the camera to control what images, videos, or slide shows are shown on the TV. 5. When nished, turn off the camera, then turn off the TV, then disconnect the cables.

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376 sites. Consequently, growth no longer requires nucleation and continues at a low overpotential. Repeated spiral growth forms low pyramids, with a steepness increasing with increasing overpotential. Figure 5.49 depicts a quadratic pyramid on an Ag(100) face. Macroscopic growth on a single crystal substrate is called epitaxy. The kinetics of electrocrystallization conforms to the above description only under precisely defined conditions. The deposition of metals on polycrystalline materials again yields products with polycrystalline structure, consisting of crystallites. These are microscopic formations with the structure of a single crystal. Whiskers are sometimes formed in solutions with high concentrations of surface-active substances. These are long single crystals, growing in only one direction, while growth in the remaining directions is retarded by adsorption of surface-active substances. Whiskers are characterized by quite

simply having the Layer 3 protocol understand it The truth is that in the real world, most data link layer protocols support only a very limited number of physical media. As you will see later, Ethernet can be run on only a few carefully specified physical media, and these specifications are part of the protocol itself. (Ethernet is therefore actually both a data link and a physical link layer protocol.) And, while other data link layer protocols such as PPP don t necessarily define the physical media they can use, by convention and common usage, there are only a few physical protocols that PPP stacks need to understand. The same holds true for other data link layer protocols. It is nevertheless true that separating interaction of the physical layer from Layer 3 has allowed for the IP protocol to exist relatively unchanged for more than 30 years. This is a remarkable achievement given the extraordinary evolution of hardware in that time period.

Fig. 5.50 Spiral growth of Cu from a 0.5 M CUSO 4 + 0.5 M H2SO4 electrolyte, 25 C, current density 15 mA c m 2 , magnification 1250x. (From H. Seiter, H. Fischer, and L. Albert, Electrochim. Acta, 2, 97, 1960)

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