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where jU (s) and jU (w) are the standard chemical potentials, identical with the standard Gibbs energies of solvation. The quantity AG r '^ s is the change in the partial molar Gibbs energy of transfer of the dissolved substance from the standard state in the reference solvent, w, to the standard state in the solvent considered, s, and is termed the standard Gibbs transfer energy. A negative value of the standard Gibbs energy of transfer for a proton, AG&jJ 8 indicates that a proton is more stable in solvent s and a positive value indicates that it is more stable in water. Some authors prefer the coefficient y^Js to the transfer Gibbs energy; this

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6 The third segment is dropped because of congestion, and the fourth segment is delayed When the first two segments are received, an acknowledgement (17000) is sent Because the previously buffered segments have been used and the two new segments are buffered, the window size is 6,000 7 After a delay because of congestion, the fourth segment is received and acknowledged Because the third segment is still missing, the acknowledgement number is still 17000 Because the two previous segments have been used and the new segment is buffered, the window size is 7,000 8 When the sender receives the second acknowledgement, the sender determines that congestion has occurred and enters the congestion avoidance phase The cnwd value is reduced by half to 2 Depending on timer values and the implementation, the missing segment may be re-transmitted immediately or later This description may be a bit daunting.

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however, this is very much the way TCP conversations occur in the real world each side is constantly attempting to adjust itself to the network conditions based on reception of data, received windows, missing segments, and so on You may need to go through this list of steps several times while following along with Figure 78 to fully understand everything that is going on Just keep in mind the fundamental principles previously discussed The sender is going to advertise the window size of data that it is willing to receive, and it is going to acknowledge the data that it has already received It is up to the sender to send at the rate of its congestion window or TCP window, whichever is less, and to recognize that a segment it has sent has been dropped based on the ACK numbers received from the receiver.

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This coefficient has various names (medium effect, solvation activity coefficient, etc.); the name recommended by the responsible IUPAC commission is the transfer activity coefficient. In this book the effect of solvation in various solvents will be expressed exclusively in terms of standard Gibbs transfer energies. In electrolytes, the ionic and the overall Gibbs transfer energies must be distinguished. These quantities are defined in the usual manner. For example, for the most usual type of electrolyte AB A + B,

You should review these steps until you are confident the process is completely clear to you In the next section, we review UDP, which, as you will see, is a much simpler protocol with far fewer features..

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7.3 User Datagram Protocol (UDP)

The Gibbs energy of an ion changes on transfer from one solvent to another primarily because the electrostatic interaction between ions and the medium changes as a result of the varying dielecric constant of the solvent. This can be expressed roughly by the Born equation (see Eq. 1.2.7), i _ i\

The original User Datagram Protocol specification is found in RFC 768, which describes the key aspects of the protocol. Unlike TCP, which has many features and can provide reliable communication across an unreliable infrastructure, UDP is far simpler and provides no guarantees of delivery. however, UDP is still a very useful transport-layer protocol. TCP provides its features and reliability at the cost of

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