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E =(RT/F)\nK (3.1.57) The relationships of the type (3.1.54) and (3.1.57) imply that the standard electrode potentials can be derived directly from the thermodynamic data (and vice versa). The values of the standard chemical potentials are identified with the values of the standard Gibbs energies of formation, tabulated, for example, by the US National Bureau of Standards. On the other hand, the experimental approach to the determination of standard electrode potentials is based on the cells of the type (3.1.41) whose EMFs are extrapolated to zero ionic strength. For example, the tabulated values for the reactants of the cell reaction (3.1.42) are AG nAgci) = -109.68 kJ moP 1 and AG / 0 (Ha , w) = -131.14 kJ-mol" 1 , both at 298.15 K.t By definition, the standard Gibbs energies of formation of H 2 and Ag are equal to zero. Thus, the standard potential of the silver-siiver chloride electrode is equal to Agci/Ag,cr = (-1.0968 x 105 + 1.3114 x 105): 9.648 x 104 = 0.2224 V. It should be noted that Eq. (3.1.52) can be obtained from the expression for the Galvani potential difference formulated in Section 3.1.2. The designation of the phases in the symbols for the individual Galvani potential differences in cell (3.1.41) will be given in brackets. The overall EMF, E> is given by the expression



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6. On each PE router, verify the state of any SDPs (see Step 4). 6a. Is it possible to get a single SDP in the Up state 7. Re-create the missing SDP and again verify that they are both admin and operationally Up.

E= 0(1')- 0(1) = 0(1') - 0(5) + 0(5) - 0(4) + 0(4) - 0(3) + 0(3) - 0(1) = A^'0 + A^0 + A^0 + A 0 (3.1.58)





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This section provides all the steps for configuring the customer-facing Service Access Points (SAPs) on the PE routers. It may not be obvious at first glance why there are so many steps. There is a chain of logic that goes something like this: A. Customer equipment connects to a VPLS via a SAP. B. SAPs can only be created on Ethernet ports that are set to access mode. C. A port with an existing interface cannot be changed to access mode. D. So we first need to remove any interfaces on network ports. If that doesn t make complete sense, don t worry because the steps below guide the way. Don t be afraid to experiment to see what kind of error messages you get if you miss a step or do it incorrectly. 1. Remove the existing network interface on PE1 that faces CE1. Use the familiar two-step process: Shut down first, then delete.

The relationship for the individual Galvani potential differences can be obtained from Eqs (3.1.12), (3.1.24) and (3.1.17) so that Eq. (3.1.58) is converted to the form (pH2=l) /ig(Pt) - pg(Ag)

*B:PE1# configure router *B:PE1>config>router# interface toCE1 shutdown *B:PE1>config>router# no interface toCE1 *B:PE1>config>router# exit *B:PE1#

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i.e. a relationship identical with Eq. (3.1.53). The correct formulation of the relationships for the Galvani potential differences leads to the same results

While the category tabs and menu items that appear below them depend on the mode the camera is in, the menu system can be broken down into ve main categories: Shooting Symbolized by a camera icon, the Shooting menu contains detailed camera setting functions you set up once for the particular way you like to shoot These functions need not be addressed every time you shoot but should be thought of as a way to customize the camera to suit your shooting style and overall preferences..

1a. What error message do you get if you try to remove an interface that is not shut down 2. Configure the port facing customer equipment as an access port.

tThe data have been recalculated from the previous standard pressure of 1.01325 x 105 to 105 Pa and those determined for unit activity on the molal scale to unit activity on molar scale (cf. Appendix A).

*B:PE1# configure port 1/1/1 *B:PE1>config>port# shutdown *B:PE1>config>port# ethernet mode access *B:PE1>config>port# no shutdown *B:PE1>config>port# exit *B:PE1#

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