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1. The session begins with host 10.10.10.1/24, which initiates a SYn that contains the sequence number 122, which is the ISn. There are only zeros in the acknowledgment field because this field is not used in the SYn segment. The window size of the sender starts as 8,192 octets. 2. The receiving host sends its ISn (286) in the sequence number field and acknowledges the sender s sequence number by incrementing the number by 1 (123); the receiver expects this value to be the starting sequence number of the data bytes that the sender will send next. This is called the SYN-ACK segment. The receiver s window size starts as 8,760. 3. When the SYn-ACK is received, the sender issues an ACK that acknowledges the receiver s ISn by incrementing the ISn by 1 and placing the value in the acknowledgment field (287). The sender also sends the same sequence number that it sent previously (123). These three segments that are exchanged to establish the connection never contain any data.

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62 actually true if acids or bases are compared in a single solvent For example, in aqueous solutions values of KA of 138 x 1(T3, 174 x 10~5 and 427 x 10~7 have been found for chloroacetic acid, acetic acid and carbonic acid, respectively; consequently, in (dilute) aqueous solutions chloroacetic acid is two orders of magnitude stronger than acetic acid which is again two orders stronger than carbonic acid These values have no absolute significance They change on transfer to another solvent and even their order can change If, for example, the protolytic reaction CH3COOH + H2O < * = CH3COO~ + H 3 O + occurred in acetic acid medium, with water as a dissolved base, then the standard state to which the activities and equilibrium constants are related would be changed Comparison of the acidity or basicity of solvents is just as difficult.

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1. From this point on, ACKs are used in every segment sent. The sender starts sending data by specifying the sequence number 123 again because this is the sequence number of the first byte of the data that it is sending. Again, the acknowledgment number 287 is sent, which is the expected sequence number of the first byte of data that the receiver will send. In this example, the sender initially sends 200 bytes of data in one segment. 2. The receiver acknowledges the receipt of the data by sending the number 323 in the acknowledgment number field, which acknowledges that the next byte of data to be sent will start with sequence number 323. It is assumed that sequence numbers up to and including 323 have been successfully received. note that not every byte needs to be acknowledged. The receiver subtracts 200 bytes from its previous window size of 8,760 and sends 8,560 as its new window size. 3. The sender sends 400 bytes of data, starting at sequence number 323.

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6.11 The Intracoastal Waterway along the coast of North Carolina was the setting for this sunset shot. I purposely dialed in 2 on the Exposure Compensation dial to render these boat docks as silhouettes against the beautiful sky and water. Taken at ISO 100, f/8, 1/30 second with a 10.8mm lens setting.

For example, alcohols react according to the equation ROH +H 3 O + ^ ROH 2 + + H2O In dilute solutions (water concentration of less than 1 mol dm" 3 ), the constant K' for this reaction in methanol is equal to 86 x 10~3 and in ethanol, 39 x 10~3 If these values were also valid in the vicinity of composition [ROH]/[H2O] = 1, then the ratio [ROH2+]/[H3O+] = /T[ROH]/[H2O] describing the proton distribution between the alcohol and water would be small Consequently, water would have a greater affinity for protons than alcohol, ie would be more basic The opposite is true The effect of the medium (solvent) on the dissolved substance can best be expressed thermodynamically Consider a solution of a given substance (subscript i) in solvent s and in another solvent r taken as a reference.

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