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173 established between hydrogen and oxonium ions in solution through a platinum electrode coated with platinum black. This coating is obtained by electrolytic deposition of platinum from an acidic solution of hexachloroplatinic(IV) acid and is saturated with hydrogen at a specific (usually atmospheric) pressure, pHr The platinum black has a double function. Firstly, its high specific surface area ensures the presence of a sufficient amount of hydrogen atoms adsorbed on the electrode; secondly, it facilitates rapid establishment of the equilibrium between the oxonium ions and elemental hydrogen (cf. Section 5.7.1). The hydrogen must be carefully purified to remove traces of sulphur(II), arsenic and mercury compounds that would poison the electrode (cf. Section 5.7.2). The potential of the standard hydrogen electrode, i.e. the potential value at / H 2 = 1 and aH3O+ = l is set by convention as zero (cf. Eqs 3.1.62 and 3.1.65). It can be seen from Eq. (3.1.65) that, when the activity of hydrogen ions increases tenfold, the potential of the hydrogen electrode increases by 2.303RT/F = 0.0591 V at 25 C. If the hydrogen pressure increases tenfold, then the potential decreases by 2.303RT/2F = 0.0295 V. Variation of the hydrogen pressure in the range of 5 per cent corresponds to a potential change from +0.63 to 0.66mV; these differences are negligible for some measurements. The hydrogen electrode is one of the electrodes suitable for pH measurements. If a hydrogen electrode saturated at unit pressure is combined with a reference electrode, then the EMF of this cell (where the reference electrode is written on the left-hand side in the scheme of the cell) is given by the equation



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le format The data structure in which digital still images and videos are stored. The Canon Powershot G11 allows RAW and JPEG formats for still images and MOV format for movies. ll ash A lighting technique where the Speedlite provides enough light to illuminate the subject in order to eliminate, reduce, or open up shadowed areas. Using a ash for outdoor portraits often brightens up the subject in conditions where the camera meters light from a broader scene. lter An accessory, usually made of glass or plastic that attaches to the front of a lens to change the color, intensity, or quality of the light that enters the camera. Filters are used to reduce glare and haze, change the color of a scene, or add a special effect like soft focus or star points to an image. are Undesirable light re ecting and scattering inside a lens that causes a loss of sharpness, contrast, or color delity to an image. Flash Exposure Bracketing FEB. Taking a series of exposures while adjusting the Flash Exposure Compensation up and/or down to ensure capturing the correct ash exposure. Flash Exposure Compensation FEC. Adjusting the ash output by +/ 3 stops in 1/3-stop increments. If images are too dark (underexposed), you can use Flash Exposure Compensation to increase the ash output. If images are too bright (overexposed), you can use Flash Exposure Compensation to reduce the ash output.





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E = H +/H 2 ~ ^ref = - 1 = lOg H+ ~ ^ref (3.2.7)

4a. Explain the results. (Hint: Check the status of the VPLS service.) 5. Re-enable the SDP that you shut down in the previous step. You may need to wait a few moments for everything to return to its previous state.

(E + Eref)F 2.303*7

*B:PE1# configure service sdp 12 no shutdown *B:PE1#

(318)

6. There are now two CE devices connected to the VPLS. Check to see if this has affected the quantity or state of the services present on each PE device.

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It would appear from Eq. (3.2.8) that the pH, i.e. the activity of a single type of ion, can be measured exactly. This is not, in reality, true; even if the liquid junction potential is eliminated the value of Eref must be known. This value is always determined by assuming that the activity coefficients depend only on the overall ionic strength and not on the ionic species. Thus the mean activities and mean activity coefficients of the electrolyte must be employed. The use of this assumption in the determination of the value of Eref will, of course, also affect the pH value found from Eq. (3.2.8). Thus, the potentiometric determination of the pH is more difficult than would appear at first glance and will be considered in the special Section 3.3.2. The hydrogen electrode can be used to measure pH values over the whole pH region. However, it is not applicable to reducing or oxidizing media or

*B:PE1# show service service-using *B:PE1#

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