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Here, KA(BH+) denotes the acid dissociation constant of a basic coloured indicator B (for the theory, see Section 147) If a given indicator is half dissociated, the value of Ho is equal to the decadic logarithm of its acidity constant times 1 For practical measurements an indicator may be used only in the range of its colour transition, ie at most in the range of the ratio cB/cBH+ from 10 to 10"1 For a larger interval of Ho values several indicators have to be used In view of the term containing activity coefficients, the acidity function depends on the ionic type of the indicator The definition of Ho is combined with the assumption that the ratio YB/YBH+ is constant for all indicators of the same charge type (in the present case the base is electroneutral; hence the index 0 in // 0 ).



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Ports identify an application service. This allows the transport layer to differentiate between application services. each process that needs to communicate with another process identifies itself to the transport layer by using one or more port numbers. A port is a 16-bit number that is used by the host-to-host protocol to identify to which higher-level protocol or application service the port must deliver incoming messages. There are two types of port numbers: Well-Known Ports Well-known port numbers belong to standard services. The port numbers range from 1 to 1023 and are assigned by the IAnA. Ephemeral Ports Client applications do not require well-known port numbers because they initiate communications with servers to well-known ports; they do not usually need to listen for connections. The host system allocates each client process a port number for only as long as the process needs the port number and then may reuse it later (hence the term ephemeral). The port numbers range from 1024 to 65535 and are not controlled by the IAnA. Because the host dynamically assigns the port number to the client application, the port number may vary each time that the client application is started. Sockets are very similar to ports, but a socket is actually a combination of IP address and port information. Sockets are used to identify the network connection between applications. Although applications on different hosts can be differentiated using IP addresses and destination addresses, it is impossible to differentiate between two sessions on the same hosts for the same application using IP addressing alone. The combination of a protocol (i.e., TCP or UDP), IP address, and port number uniquely identifies a socket on each end. Figure 7.12 illustrates an example of a server using sockets to uniquely identify client conversations.





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Thus, the acidity function does not depend on each individual indicator but on the series of indicators The acidity function is determined by successive use of a range of indicators Hammett and Deyrup started with / -nitroaniline, the pKAx of which in a dilute aqueous solution is 111 (the solvolysis constant has been identified with the acidity constant) Since in a dilute aqueous solution, = 7B YBH+ ~ 1 > the acidity function for the aqueous media goes over to the pH scale By means of p-nitroaniline, the acidity constant of another somewhat more acidic indicator is obtained under conditions such that both forms of each indicator are present at measurable concentrations Then Ho as well as the pKAl of the other indicator is determined by using Eq (1440) By means of this indicator, values of Ho not accessible with / -nitroaniline may be reached.

Figure 7.12 Multiple instances of the same application can be initiated between the same hosts because TCP and UDP use both source and destination ports to uniquely identify each session. The destination port is the same for each application session, but the source ports for each session are unique.

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The Ho scale is further extended by using a third indicator and its pKA3 is determined in the same way (see Fig 111) The concentration ratios are determined photometrically in the visual or ultraviolet region Figure 112 shows the dependence of Ho on the composition of the H2SO4-H2O mixture and was obtained as indicated above 147 Acid-base indicators The interest in colour indicators has recently increased as they are used for the direct determination of pH (acid-base indicators) and free calcium ions (fluorescent derivatives based on the calcium chelator EGTA as metallochromic indicators) in biological systems at cellular level..

Enable Telnet client 1 application. Create client socket TCP,138.120.191.233,15633. Connect to server. Enable Telnet client 2 application. Create client socket TCP,138.120.191.233,15322. Connect to server.

Fig. 1.12 Acidity function H() for the mixture H 2 SO 4 -H 2 O as a function of the composition. (According to L. P. Hammett and M. A. Paul)

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Enable Telnet server application. Create socket address TCP,138.120.168.100,23. Listen to client requests: incoming request from Client 1 Conversation: TCP, 138.120.168.100,23,138.120.191.233,15633, Incoming request from Client 2 Conversation: TCP, 138.120.168.100,23,138.120.191.233,15322.

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