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the dry state) discrete hydrophilic regions, separated by narrow hydrophobic channels. The hydrophilic regions are formed by a specific aggregation of the ionogenic side chains on the perfluorinated backbone, whereas the channels are composed of hydrophobic fluorocarbon chains (see the polymer formula above). The individual macromolecular chains are thus interconnected by the embedded clusters into a more complicated supramolecular network (Fig. 2.20). This, moreover, explains why Nafion and related materials are practically insoluble in water, in spite of the absence of regular interchain bonds as in classical cross-linked ion-exchange polymers (e.g. polystyrene sulphonate). By swelling with aqueous electrolyte, cations (and, to lesser extent, also anions) penetrate together with water into the hydrophilic regions and form spherical electrolyte clusters with micellar morphology. The inner surface of clusters and channels is composed of a double layer of the immobilized SO^ groups and the equivalent number of counterions, M + . Anions in the interior of the clusters are shielded from the SO^ groups by hydrated cations and water molecules. On the other hand, anions are thus



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several route metrics used in BGP for route selection, and they are covered in detail in Alcatel-lucent s BGP course.

Fig. 2.20 The Gierke model of a cluster network in Nafion. Dimensions are expressed in nm. The shaded area is the double layer region, containing the immobilized SO3 groups with corresponding number of counterions M + . Anions are expelled from this region electrostatically





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In the second use case, an enterprise has a large OSPF network with multiple local Area network (lAn) segments. The enterprise also has multiple connections to two ISPs (AS 47 and AS 395). In this configuration, the enterprise will often run BGP to manage the connections with their ISPs. BGP policies are used to determine the path that is used for traffic leaving the enterprise. One ISP may be preferred for some routes, or one ISP may be used as a primary connection to the Internet, with the other ISP used as a backup, as shown in Figure 10.7.

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134 'trapped' inside the clusters owing to the high electrostatic barrier in the hydrophobic channel where the shielding effect is suppressed. This makes it clear why the channels are preferentially conductive for cations, i.e. the polymer membrane (despite the presence of free anions) is not anionconducting. Diffusion of cations in a Nafion membrane can formally be treated as in other polymers swollen with an electrolyte solution (Eq. (2.6.21). Particularly illustrative here is the percolation theory, since the conductive sites can easily be identified with the electrolyte clusters, dispersed in the nonconductive environment of hydrophobic fluorocarbon chains (cf. Eq. (2.6.20)). The experimental diffusion coefficients of cations in a Nafion membrane are typically 2-4 orders of magnitude lower than in aqueous solution.

Figure 10.7 The customer has multiple BGP connections to different providers. Internally, the customer routers will determine the best route based on OSPF, and BGP will be used to determine the best external AS to forward packets to for Internet routes.

The rst is to try to have any implied subject motion moving toward the center of the frame This adds balance and a direction for the viewer s eye to follow The opposite approach may weigh the image down in that direction and give the photo an unbalanced feel The second applies when shooting landscapes with the sky as an element of the scene If I have an incredible sky, I place the horizon on or near the lower horizontal line If I have a blah sky but very good light, I move the horizon up to the higher horizontal line and search out some interesting element in the good light for my foreground..

References Conway, B. E., Proton solvation and proton transfer in solution, MAE, 3, 43 (1964). Dekker, A. J., Solid State Physics, Prentice-Hall, Englewood Cliffs, 1957. Eisenberg, A. E., and H. L. Yeager (Eds), Perfluorinated Ionomer Membranes, ACS Symposium Series 180, ACS, Washington, 1982. Glasstone, S., H. Eyring, and K. J. Laidler, Theory of Rate Processes, McGrawHill, New York, 1942. Hertz, H. G., Self-diffusion in solids, Ber. Bunsenges., 75, 183 (1971). Hladik, J. (Ed.), Physics of Electrolytes, Academic Press, New York, a multivolume series, published since 1972. Huggins, R. A., Ionically conducting solid state membranes, AE, 10, 323 (1977). Inman, D., and D. C. Lovering (Eds), Ionic Liquids, Plenum Press, New York, 1981. Kittel, C , see page 104. Laity, R. W., Electrochemistry of fused salts, /. Chem. Educ, 39, 67 (1962).

Within the enterprise network, internal routing information is exchanged with OSPF. The enterprise networks are summarized as 100.200.0.0/20 and advertised to the ISPs and onward to the Internet with BGP. In this scenario, the enterprise uses a private AS number, and its routes are advertised by the ISPs using their AS numbers. The full set of Internet routes is not exported into OSPF. Instead, a default route is advertised by the Internet-connected routers. Some subsection of the BGP routes that are received may be advertised into the enterprise in order to influence the route for traffic that egresses the enterprise network.

Linford, R. G., Electrochemical Science and Technology of Polymers, Vol. 1 & 2,

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