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where c(l) and c(2) are the concentrations at points 1 and 2. The potential difference formed at the junction of two electrolytes with different but constant composition and dissolved in the same solvent is very important in electrochemical measurements. Solutions can come into contact either directly (a suitable experimental arrangement must be used to prevent mixing through convection see below) or can be separated by a diaphragm with sufficiently large pores. This diaphragm can be a glass frit, ceramic disk, etc., and is permeable for all the components of the system and simply prevents mechanical mixing. Thus, the system consists of two solutions, where the concentration is constant everywhere, and of a transition region at their contact, where diffusion occurs. This region has a thickness of d and is either free or enclosed in the pores of a diaphragm: Solution 11 diaphragm | solution 2 x =p x =q Here, x is the coordinate normal to the diaphragm, so that d = q p. The liquid junction potential A0 L is the diffusion potential difference between solutions 2 and 1. The liquid junction potential can be calculated for more complex systems than that leading to Eq. (2.5.31) by several methods. A general calculation of the integral in Eq. (2.5.30) is not possible and thus assumptions must be made for the dependence of the ion concentration on x in the liquid junction. The approximate calculation of L. J. Henderson is

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113 often used, assuming that the ion concentration in the liquid junction varies linearly with x between the values in the two solutions: ct(x) = Ci(p) + [cXq) C;(p)] Substitution into Eq. (2.5.30) yields

The configuration for the interfaces and OSPF information for router r1 are shown in Listings 9.4 and 9.5. First, you must create the interfaces that will participate in the OSPF routing protocol. On router r1 we have created the system interface and two other interfaces, toR2 and toR5. You must assign them to a particular port and give them an IP address. note that the system interface does not require a port. next, you have to configure the interfaces for OSPF. You do this by creating an OSPF area ID, 0.0.0.0 in this case, and assigning interfaces to this area. As mentioned previously, the interfaces need to be configured as type point-to-point since they are Ethernet and will default to OSPF interface type broadcast by default.

(2.5.33)

*A:AIRP_R01>config>router# info ---------------------------------------------#-------------------------------------------------echo IP Configuration

7 =1

(continued)

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1= 1

#-------------------------------------------------interface L1 address 172.16.2.1/24 loopback exit interface L2 address 172.16.3.1/24 loopback exit interface system address 172.16.1.1/32 exit interface toR2 address 172.31.12.1/24 port 1/1/2 exit interface toR3 address 172.31.13.1/24 port 1/1/3 exit interface toR4 address 172.31.14.1/24 port 1/1/4 exit interface toR5 address 172.16.15.1/24 port 1/1/1 exit

E ZiUtlCiiq) ~ Ci(p)]

(continued)

E Z^M^CK )-^)]

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