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165 as the procedure following from Eq. (3.1.39) or from Eqs (3.1.45) to (3.1.49). It should be noted that all terms concerning the electrons in the metals as well as those connected with the metals not directly participating in the cell reaction (Pt) have disappeared from the final Eq. (3.1.49). This result is of general significance, i.e. the EMFs of cell reactions involving oxidationreduction processes do not depend on the nature of the metals where those reactions take place. The situation is, of course, different in the case of a metal directly participating in the cell reaction (for example, silver in the above case). For cell reactions in general, both approaches yield the equation for the EMF: RT ln (3.1.60) nr where E is the standard EMF (standard cell reaction potential), n is the charge number and Q is the quotient of the activities of the reactants in the cell reaction raised to the appropriate stoichiometric coefficients; this quotient has the same form as the equilibrium constant of the cell reaction. For practical reasons it is often useful to separate the EMF of a galvanic cell into two terms and assign each of them to one of the electrodes. The half-cell reactions provide a basis for unambiguous separation. The equation for the overall EMF is converted to the difference between two expressions, in which the expression corresponding to the electrode on the left is subtracted from the expression corresponding to the electrode on the right. Thus, for example, it follows for Eq. (3.1.59), with inclusion of a term containing the relative hydrogen pressure, that ^ - ( w ) - RT In qcl-(w)



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2a. There are only two states for a port: One is access mode. What is the name of the other mode (Use the CLI Help!) 2b. What error message do you get if a port is not shut down when you try to change modes 3. On PE2, configure the corresponding customer-facing port as an access port. This exercise assumes that Device 4 is connected to port 1/1/1. If you are using

(3.1.61) The terms Agci/Ag,ci- and EH+/H2 are designated as the electrode potentials. These are related to the standard electrode potentials and to the activities of the components of the system by the Nernst equations. By a convention for the standard Gibbs energies of formation, those related to the elements at standard conditions are equal to zero. According to a further convention, cf. Eq. (3.1.56), JI2,+(W) - AG}>(H+, w) = 0 Then ) (3.1.63) (3.1.62)





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a different port, you will need to adapt the commands given below. (Also, if you have configured a network interface on that port, you will need to remove it first.)

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166 It follows from Eqs (3.1.53) and (3.1.55) that RT EAgcuAg,ci- = ^Agci/Ag,ci- - In cr(w) r RT RT ln H Euvu2 = ~y{naH+~JP ^ 2 (3.1.64) (3.1.65)

*A:PE2# configure port 1/1/1 *A:PE2>config>port# shutdown *A:PE2>config>port# ethernet mode access *A:PE2>config>port# no shutdown *A:PE2>config>port# exit *A:PE2#

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which are the Nernst equations. They will be discussed in detail in Section 3.2. It should be recalled that, in contrast to standard electrode potentials, which are thermodynamic quantities, the electrode potentials must be calculated by using the extrathermodynamic expressions described in Sections 1.3.1 to 1.3.4. The electrode potentials do not have the character of Galvani potential differences, but are simply operational quantities permitting simple calculation or interpretation of the EMF of a galvanic cell and are well suited to the application of electrochemistry in analytical chemistry, technology and biology. In the subsequent text the half-cell reactions will be used to characterize the electrode potentials instead of the cell reactions of the type of Eq. (3.1.42) under the tacit assumption that such a half-cell reaction describes the cell reaction in a cell with the standard hydrogen electrode on the left-hand side. The EMF of a cell is calculated from the electrode potentials (expressed for both electrodes with respect to the same reference electrode) as the difference of the potentials of these electrodes written on the right and left in the scheme:

A general first step for troubleshooting services is to check that nothing has been (accidentally) left in a (shut)down state. The next step is to check that nothing was skipped or missed while building the configuration. 1. IGP Verification Confirm that OSPF is running throughout the provider network (i.e., just PE1 and PE2 in this case). Confirm that routes for every interface appear in the routing table. Confirm that all interfaces within the provider network respond to a ping. (Remember that customer-facing ports are now operating as SAPs, not network interfaces.) 2. LDP Verification Confirm that LDP has successfully exchanged all labels that will be necessary for PE1 and PE2 to send data back and forth. Each router needs a pair of labels one to reach the far router and one offered to the far router to send data back to the local router.

^cell = ^rhs ^lhs (3.1.66)

*B:PE1# show router ldp bindings active ======================================================== Legend: (S) - Static ======================================================== LDP Prefix Bindings (Active) ======================================================== Prefix Op IngLbl EgrLbl EgrIntf EgrNextHop -------------------------------------------------------140.10.0.1/32 Pop 131071 ---150.10.0.1/32 Push -131071 1/1/2 140.10.0.98 -------------------------------------------------------No. of Prefix Bindings: 2 ======================================================== *B:PE1#

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