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Correction for the effect of the potential difference in the diffuse layer is carried out by plotting log |/| against E (j)2 rather than against E It can be seen from Fig 58 that the corrected curves are identical for both electrolytes The effect of the electrical double layer on the reduction of polyvalent anions such as S2O82~ is especially conspicuous Here it holds that az -zOx<l At potentials corresponding to a negatively charged electrode (E<Epzc), the potential of the outer Helmholtz plane is 0 2 <O and its absolute value in dilute solutions increases with increasing negative potentials This leads to a paradoxical situation: the rate of the cathodic reaction decreases with increasing negative potential (see Fig 59) The Frumkin theory of the effect of the electrical double layer on the rate of the electrode reaction is a gross simplification.



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system The G11 autofocus (AF) performance is excellent, and AF selection is customizable Getting tack-sharp focus, of course, depends on three factors: the resolving power of the lens (its ability to render ne details sharply), the resolution of the image sensor, and the resolution of the printer for printed images While the resolution of printers is beyond the scope of this book, I can address the other two factors The G11 has excellent image sensor capabilities provided by the new 10MP sensor and DiG!C 4 processor that yields lower noise due to the new Dual Anti-Noise System In terms of setting focus on the G11, you have two choices: you can let the camera select the AF point automatically, or you can manually move and resize the AF frame to change it.

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For example, the electrode reaction does not occur only at the outer Helmholtz plane but also at a somewhat greater distance from the electrode surface More detailed considerations indicate, however, that Eq (5320) can still be used to describe the effect of the electrical double layer as a good approximation Various approaches to the theory of electrode reactions with participation of adsorbed react ants are beyond the scope of the present book The effect of of the electrical double layer is negligible for chemisorption (see Section 433 and 571) For semiconductor electrodes and also for the interface between two immiscible electrolyte solutions (ITIES), the greatest part of the potential difference between the two phases is represented by the potentials of the diffuse electric layers in the two phases (see Eq 4518).

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The rate of the charge transfer across the compact part of the double layer then depends very little on the overall potential difference The potential dependence of the charge transfer rate is connected with the change in concentration of the transferred species at the boundary resulting from the potentials in the diffuse layers (Eq 435), which, of course, depend on the overall potential difference between the two phases In the case of simple ion transfer across ITIES, the process is very rapid being, in fact, a sort of diffusion accompanied with a resolvation in the recipient phase..

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References All references from page 253 Armstrong, F. A., H. A. O. Hill, and N. J. Walton, Reactions of electron-transfer proteins at electrodes, Quart. Rev. Biophys., 18, 261 (1986). Delahay, P., see page 266. Dogonadze, R. R., Theory of molecular electrode kinetics, in Reactions of Molecules at Electrodes, p. 135, see page 253. Dogonadze, R. R., L. I. Krishtalik, and V. G. Levich, Present state of the theory of the elementary step of electrode reactions (in Russian), Zh. Vsesoyuz. Khim. Obsh., 16, 613 (1971).

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