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where K is the disproportionation constant. An inert electrode immersed in a solution containing species A, B and C will attain a potential corresponding to both of equilibria (3.2.25): E = A,B + ^ l n ^ = Elc + ^ l n ^ (3.2.27) F aB F ac If the system initially contains only form C with concentration c0, to which the oxidant is added, then the overall degree of oxidation is (3 = (2[A] + [B])/c0. If activities are set equal to concentrations, then the potential E can be expressed in terms of j8:

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15. All of the following are reasons that using BGP between ASes is preferable to using IGP route re-distribution except ______. A. Route re-distribution loses the metrics of the original IGP. B. Route re-distribution can lead to routing loops. C. BGP provides a consistent interface for route exchange across various ASes. D. Route re-distribution provides for greater policy control.

/3l [(j3l) + 4j3(2/W -j3 + 1 [03 - I) 2 + 4)3(2 - j3)*:]1/2

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This dependence is shown in Fig. 3.10. The usual dependence for n = 2 is obtained for complete disproportionation, that is K 1. With decreasing K, the E~P curve changes and at K = \ assumes the usual shape for n = 1. For small K values three inflection points appear on the curve. This situation often occurs for organic quinones. Form B is then termed the semiquinone. A typical inorganic redox system of this type involves the equilibrium between metallic copper and copper(II) ions. In the absence of a complexformer the disproportionation constant is large and a solution of Cu+ ions is very unstable. However, in the presence of ammonia, copper(I) ions are bonded in a complex, constant K decreases and the E-(3 curve exhibits three inflection points.

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1. Which of the following accurately describes a P device A. It is used exclusively by the customer. B. It is responsible for adding and removing labels. C. It swaps label information and forwards packets. D. It creates an LSP in the provider network. 2. Which of the following is false regarding an SDP A. It provides transport tunnel encapsulation. B. It is specific to a single service. C. The SDP ID is locally unique. D. LDP can be used as the signaling protocol. 3. Which of the following is not an accurate description of a VPN A. A series of point-to-point tunnels configured on client equipment B. A tunnel technology created in a provider network C. A function of MPLS networks to create private communities of users D. Any network that includes encryption 4. Which of the following is false regarding LDP A. It is used to define unidirectional paths through the network. B. It is a protocol specifically intended for label distribution. C. It is the only method for distributing labels in an MPLS network. D. It describes a path through the MPLS network based on the IGP path.

-8 0.8 1.2 Overall oxidation degree,/3 1.6 2.0

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Fig. 3.10 Dependence of the potential function v = (2F/2.3RT) [E K A,B + B,C)] on the overall oxidation degree J3 for a system with disproportionation. The semiquinone formation constant K' = l/K is indicated at each curve

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