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home address. Each address uniquely identifies a particular house somewhere in the world, and no two addresses are exactly alike. Similarly, the addressing is hierarchical, having a street address, a city, and a country (and a state, if you are in the United States). however, since these addresses are meant to be used solely by machines, they use only numeric addresses. In order to get data from one addressed host to another, you need a protocol that understands the addressing and knows how to get from point A to point B. On the Internet, this protocol is known appropriately enough as the Internet Protocol (IP), and the addresses are known as IP addresses. An example of an IP address is 138.120.105.45, and this address must be unique to a single computer. Delivering packets to a given IP address is again very similar to the methods that one would use to deliver mail to a person s home. The distribution of IP addresses is supervised by a centralized authority known as the Internet Assigned Numbers Authority (IANA), the way home addresses are issued by local government agencies. Indeed, the actual issuance of IP addresses is handled by different delegated Regional Internet Registry (RIR) agencies in different parts of the world, as shown in Figure 1.6.



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particle in the neighbouring phase, ew(a), ev(j8), and v(s) are the changes in the thermal vibrational energies of the particle at the interface as a result of formation of the free surface and contact between the phases, N(a) and N(p) are the numbers of particles per unit surface area for the free surface of phases a and /3, c(s) is the bond energy between the particles of phases a and jS in the interphase and N(s) is the number of such bonds per unit surface area at the interphase. If we assume that N(a) = N((3) = N(s)9 that species at the surface have only one free bond (n0-ns=l) and that ec er, v, then (s) (4.2.3)

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This expression can be roughly interpreted as the difference between the Gibbs energy of adhesion of the two phases and the sum of the Gibbs energies of cohesion for the two phases. These considerations can also be used to derive the Dupre equation, where AG(s) is the Gibbs energy of adsorption of the solvent per unit area of the metal surface: AG(s) = y m / a + y 1 / a - y (4.2.4)

ARIN 96/8 to 99/8, 204/8 to 209/8 AMNIC 41/8, 196/8

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where ym/a is the interfacial tension of the metal-air interface, y1/a is the interfacial tension of the solution-air interface and y is the interfacial tension of the metal-solution interface. Now the relationship between the interfacial tension and the composition of the two phases in contact will be analysed thermodynamically by using the approach of J. W. Gibbs. The interphase can be considered as a particular phase s of thickness h. This phase differs from the homogeneous phases only in that the effect of pressure is accompanied by the effect of the interfacial tension y. Consider a rectangle with sides h (perpendicular to the interphase) and / (parallel with the interphase) located perpendicular to the interphase. The force acting on the rectangle is not equal to the product phi (as for an area in the bulk of the solution) but phi yl. If the volume of the interphase V(s) is increased by dV(s) by increasing the thickness of the interphase by dh, then area A = V(s)/h increases by cL4. The overall work, Wy connected with this process consists of volume work accompanying the increase in the thickness of the interphase and volume and surface work connected with an increase of the surface area: W(s) = -pA dh + {-ph + y) cL4 = -p dV(s) + y dA (4.2.5)

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Because of this formation, a different definition of the enthalpy must be introduced for the interphase, differing from the usual expression for a homogeneous phase: H(s) = U(s) + pV(s) - yA (4.2.6)

LACNIC 186/8, 187/8, 189/9, 190/8

where U(s) is the internal energy of the interphase. For the differential Gibbs energy of the interphase we have dG(s) = d[//(s) - TS(s)] = dU(s) + p dV(s) - V(s) dp - y dA - A dy - T dS(s) - 5(s) dT + 2 ft d^i(s) (4-2.7) /=o where nf-(s) is the amount of the ith component of the system in phase s and n is the total number of components. As dU(s) + p dV(s) -ydA-T it follows that dG(s) = ~S(s) dT + V(s) dp - A dy + J) pg dnt(s)

APNIC 114/8 to 126/8

dS(s) = 0

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