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In this case, theory predicts that the R value can be changed, even for non-absorbing films, as a result of existence of a third phase with different refractive index interspaced between the electrode and electrolyte Therefore, the entire observed decrease in reflectivity R is not necessarily caused by the absorption of radiation in the film This approximation, is, however, reasonably acceptable when the film is supported by a highly reflective phase, such as smooth metal electrode In general, two basic experimental arrangements of reflective spectroelectrochemistry are possible: (a) The excitation beam passes first through a window in the electrochemical cell, then through the electrolyte and is finally reflected from the surface of the electrode back into the electrolyte phase (specular external reflectance) There is a sufficient number of suitable substances for the preparation of electrodes, electrolytes and windows for working in the ultraviolet and visible regions.



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Figure 8.21 Three different types of static routes are used from CE to PE and from PE to PE in this lab exercise.

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More problems are encountered in the infrared region, as practically all electrolytes absorb infrared radiation so strongly that external reflection spectra can be studied only in cells with a very thin (1-10 \xm) layer of electrolyte between the window (usually Si, Ge, ZnSe, CaF2) and the electrode (b) The excitation beam passes through the electrode material and is reflected once or twice from the interface with the electrolyte back into the electrode material (internal or attenuated total reflection) This method requires the use of an optically transparent electrode Internal reflectance of infrared radiation can be studied, for example, on a germanium electrode; other materials such as carbon and various metals have such high absorption coefficients for infrared radiation that they can be used in only very thin layers (5-30 nm) fixed to transparent support materials Vacuum deposited gold layer on a Ge electrode is the most common arrangement.

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Consider for a moment the CE1 router. Since there is only one single connection to the rest of the (Inter)network, the next-hop address would always be the same for every single static route. It seems pointless to have many, many static routes all giving the same next hop. A default route provides a solution a single routing entry that effectively says: Any other destination uses [PE1] as the next hop. This route will be used for any destination subnet that isn t local to CE1. next, let s look at the network from PE2 s perspective. All hosts in the subnet 140.10.0.0/24 exist somewhere within ISP 1. Exactly where a host resides within ISP 1 isn t a concern for PE2; that s PE1 s job to sort out. All PE2 needs to know is that any address within 140.10.0.0/24 should be forwarded to PE1 as the next hop. PE2 uses an aggregate route for the /24 subnet without considering whether every single possible

In practice, a compromise between the electrical conductivity and infrared absorbance must always be found..

host within that range actually exists (In fact, there may be many addresses and entire blocks for which no hosts exist!) The key point of the aggregate route is that there are no hosts outside of ISP 1 for the 1401000/24 range Likewise for PE1: It should be configured so that traffic for all possible hosts in the 1501000/24 range is sent via PE2 This set of lab exercises makes use of all three types of routes (simple, aggregate, and default) to get full connectivity between the routers with a minimum number of entries in each router s routing table The CE device uses a default route toward PE1; PE1 will use simple static routes toward the subnets associated with CE1; and both PE routers will use aggregate routes for the neighbor s IP subnet.

The relative changes in reflectance at the electrode are usually very small, typically of the order of 10~4-10~2 per cent, and thus a special technique must be used to measure these differences; this is based primarily on signal modulation and lock-in detection The simplest modulation method is based on mechanical interruption of the excitation light beam; this approach has a disadvantage in that it in no way increases the surface sensitivity of reflectance spectroscopy Thus it is preferable to employ signal modulation by periodic changes in the electrode potential (electrochemically modulated reflectance spectroscopy) A further approach to modulation involves application of polarized excitation radiation This modulation depends on periodic changes in the polarization plane of the radiation between the directions perpendicular to and parallel to the plane of reflection of the beam.

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