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, 1970) developed a theory of the resting potential of axon membranes, based on the assumption that the strength of the electric field in a thin membrane is constant and that ion transport in the membrane can be described by the Nernst-Planck equations It would appear that this approach does not correspond to reality it has been pointed out that ions are transported through the membrane in channels that are specific for a certain kind of ion Thus, diffusion is not involved, but rather a jumping of the ions through the membrane, that must overcome a certain energy barrier In deriving a relationship for the resting potential of the axon membrane it will be assumed that, in the vicinity of the resting potential, the frequency of opening of a definite kind of ion channel is not markedly dependent on the membrane potential.



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This requires the use of more modern routing protocols The routing protocol used must be able to satisfy the following: The routing protocol must be able to carry the extended prefixes with each subnet advertised..

The transport of ions through the membrane can be described by the same equations as the rate of an electrode reaction in Section 522 It will be assumed that the resting potential is determined by the transport of potassium, sodium and chloride ions alone The constants fcp are functions of the frequency of opening and closing of the gates of the ion-selective channels The solution to this problem will be based on analogous assumptions to those employed for the mixed potential (see Section 584) The material fluxes of the individual ions are given by the equations.





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The routers themselves must make forwarding decisions based on the longest match. The routing protocol must be able to perform summarization to support route aggregation. routing protocols such as osPF and Is-Is support the use of VLsm. rIPv1 does not support the use or deployment of VLsm; however, rIPv2 does support the use of VLsm. Let s take a look at another example where VLsm is useful. In the example in Figure 5.20, the organization is assigned the network IP address of 172.16.0.0/16, and it plans to design and deploy a VLsm network. Five subnets are required, each with a requirement of 2,000 hosts.

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Subnet 1 172.16.0.0/19

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where A is a constant and e is the activation energy of hopping. The exponent n is usually 1/4 or 1/3 (it is the reciprocal of the effective dimensionality of the space in which the charge transport occurs). The charge transport in a conjugated chain and the interchain hopping is explained in terms of conjugation defects (radical or ionic sites), called solitons and polarons. Several possible conjugation defects are demonstrated in Fig. 5.33 on the example of trans -polyacetylene. A soliton is an electroneutral radical site with a spin equal to 1/2 connected to the rest of the chain by somewhat longer bonds; the charge and the bond lengths are, however, disturbed also in the close surroundings of the defect, hence the soliton extends over about 15 ( CH ) units. If we remove or add an electron to the soliton, a zero spin and the corresponding charge appears (charged soliton). Two neutral solitons can recombine and the chain defect is cancelled. On the other hand, charged and neutral solitons in neighbouring sites form a stable pair called polaron. Both the solitons and polarons are mobile along the chain, but a soliton, unlike a polaron, moves virtually without overcoming energy barriers. If the number

Subnet 3 172.16.64.0/19

of polarons in the chain increases, they can interact basically in two ways: two polarons can either form two charged solitons or a new stable zero-spin defect called bipolaron The electronic band structure of a neutral polyacetylene is characterized by an empty band gap, like in other intrinsic semiconductors Defect sites (solitons, polarons, bipolarons) can be regarded as electronic states within the band gap The conduction in low-doped polyacetylene is attributed mainly to the transport of solitons within and between chains, as described by the 'intersoliton-hopping model (IHM)' Polarons and bipolarons are important charge carriers at higher doping levels and with polymers other than polyacetylene There exist numerous conjugated macromolecules showing high electronic conductivities after doping Materials thus prepared are also termed 'synthetic metals' (their significance is documented, for example, by the existence of a journal of the same name).

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