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However, the designation of a given substance as an acid or base, weak or strong, lacks a logical foundation Of decisive importance is the behaviour of a given substance with respect to a given solvent, where it can act as a strong or weak acid or base This generalization follows from the concepts of Br0nsted and Lowry..



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Objective In this exercise, you will design and implement an IP network addressing scheme to support the communications between the labeled routers shown in Figure 5.33. The IP addressing scheme will be used in the subsequent lab exercises throughout the book. Validation You will know you have succeeded by verifying your answers with the solutions provided in Appendix B.





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The biggest challenge I nd is establishing a base exposure that still retains detail in the highlights of performers as they move in and out of the strong spotlights on the stage. To this end, I also experiment with white balance settings even though I might be getting good results with AWB. In the past, I ve gotten great results with Tungsten and custom white balances, so I alternate among the three as stage lighting changes to establish which is best. A lot of times the stage lighting is warm, and a Tungsten white balance cools things off a bit yet still produces pleasing skin tones. At concerts, I use the Auto Exposure Lock button, setting the exposure on the hottest highlight area of the performer s body. Alternately, you can use the Spot meter to determine the exposure of the face. For all indoor events on a stage, I shoot wide open at the lowest ISO that I can set and still get 1/60 second or slower at f/2.8 with my built-in IS lens. With the high ISO range of the PowerShot G11, I m excited about shooting concerts now at exposure combinations and low noise levels not previously possible.

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Water The pH range that can reasonably be used extends from 0 to 14, with the neutral point at pH 7 A solution with p H < 7 is acidic and with pH > 7 is basic The commonest strong acids are HC1O4, H2SO4, HC1 and HNO3; strong bases include alkali metal and tetraalkylammonium hydroxides Methanol and ethanol The self-ionization reaction is ROH2+ + RO~ The pHMe range is about 95 and the pHEt about 83 HC1O4 continues to be a strong acid and HC1 becomes a 'medium strong' acid (pKAMe = 12, p # A E t = 21) Acetic acid has the values of pKAMe = 97 and pKABt = 104, ie it is much weaker than in water Strong bases include the alkali metal alcoholates, as they introduce RO~ anions, the conjugate base of alcohol.

CE1 Port 1/1/1 ISP 1 PE1 Port 1/1/1 Port 1/1/2 ISP 2 PE2 Port 1/1/2

Water is a weak base in ethanol (pKA = 03) Liquid ammonia Self-ionization occurs according to the equation 2NH3* NH4+ + NH2~ and the pH range at -60 C is 32 units Acids that are weak in water, such as acetic acid, are strong in ammonia and acids that are very weak in water become medium strong in ammonia Strong bases include potassium amide, introducing NH2~ ions, while hydroxides are weak bases (a KOH solution with a concentration of 10~2 mol dm"3 has a pHNH3 value of about 245) If an amphiprotic solvent contains an acid and base that are neither mutually conjugate nor are conjugated with the solvent, a protolytic reaction occurs between these dissolved components Four possible situations can arise If both the acid and base are strong, then neutralization occurs between the lyonium ions and the lyate ions.

note that in Figure 5.33, only the labeled routers joined by solid lines will actually be configured (i.e., PE1, PE2, CE1). The other routers, joined by dashed lines, represent the multitude of additional connections that might exist in a real-world scenario with many IsPs. The focus of Figure 5.33 is the two IsPs: IsP 1 and IsP 2. A more typical network diagram would show routers that are entirely contained within the IsP s core network, having no connections to any customers. such routers are referred to as Provider (P) routers and serve as transit points to other provider routers. Provider Edge (PE) routers have at least one connection to the IsP s customers and provide Internet and other network access for these customers. For the purposes of these lab exercises, all the IsP routers are considered PE routers.

If the acid is weak and the base strong, the acid reacts with the lyate ions produced by the strong base The opposite case is analogous A weak acid and a weak base exchange protons: Strong acid + strong base Weak acid + strong base Strong acid + weak base Weak acid 4- weak base.

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