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128 2.6.4 Ion transport in polymers Ion conducting polymers (polymer electrolytes) attract increasing attention not only from the academic point of view, but also for their prospective applications in batteries, sensors, electrolysers and other practical devices. Although the ion conducting polymers can formally be regarded as 'solid electrolytes', the mechanism of ion transport is different from that in the above-discussed inorganic crystals with lattice defects, and it resembles the ion transport in liquid media. This follows from the fact that ions are transported in a polymeric host material, which is essentially not as rigid as the defect crystal of the classical inorganic solid electrolyte, i.e. the host motions or rearrangements virtually contribute to the ion transport as well. The ion conducting polymers therefore present a special class of electrolytes with features intermediate between those of solid (defect crystals) and liquid (solutions, melts) electrolytes. The ion conducting polymers contain, besides the organic polymeric backbone, ions in more or less strong interactions with the polymer, and in some cases also solvent molecules. Ion solvating polymers. Polymers that are conducting even in the dry state, i.e. without attached solvent molecules, are termed ion solvating {or ion-coordinating) polymers. These contain electronegative heteroatoms (prevailingly oxygen, sometimes also nitrogen, sulphur, or phosphorus), which interact with cations by donor-acceptor bonds similar to those in solvated ions in solutions. The complexes of ions with polymers are simply formed by dissolving inorganic salts in suitable polymeric hosts. The most important solvating polymeric hosts are two polyethers: poly(ethylene oxide) (PEO) and poly(propylene oxide) (PPO):



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However, BGP can easily be configured to prefer routes advertised over one link by changing the origin of the routes advertised over one of the links. If the origin of routes advertised over one link is preferred over the origin of those advertised over a different link, for example, then that link will be used as the primary route. An ISP might want to do this because of certain policy arrangements with a neighboring ISP.

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CH CH2 O CH3 PEO PPO Lithium perchlorate is dissolved in PEO owing to the coordination of Li+ cation by oxygen atoms in the polymeric chain. The complex thus formed has the helical structure (Fig. 2.18), and exhibits ionic conductivities of up tol(T 4 S/cmat60 o C. The mechanism of ion transport in such systems is not fully elucidated, but it is presumably dependent on the degree of crystallinity of the polymeric complex (which further depends on the temperature and the salt type). The ionic conductivity was initially attributed to cation hopping between fixed coordination sites in the depicted helical tunnel, i.e. in the crystalline part of the polymer. A more detailed analysis revealed, however, that the cation hopping

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This is only a very simple example of the sorts of policy decisions that can be made using BGP attributes. Further discussion of BGP policies is beyond the scope of this book, but you can understand the basic operation of BGP by keeping in mind just these three mandatory attributes. Of course, many more attributes are available that can be used to influence BGP routing policies. In fact, it is the use of these additional attributes that complicates the configuration and use of BGP. BGP is an extraordinarily powerful routing protocol, and newcomers to network routing often want to see it used in their network. However, not every connection to the Internet requires BGP, and its power can also lead to unnecessary complexity. As with many things, often the simpler solution is the best solution. In the next section, we review when to use and when not to use BGP.

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When should you use BGP As mentioned above, BGP can accommodate virtually any number of policies. This flexibility can be somewhat of a double-edged sword. BGP is administratively much more complex than an IGP. BGP updates include path information that is used for routing policy enforcement and loop detection between ASes. Adding to the complexity of BGP is the fact that topology and routing table sizes become much larger than in an IGP environment. The increased size of the tables means that factors such as CPU loading, memory utilization, update generation, and route processing have greater implications in BGP. Keeping these factors in mind, there are several considerations you need to account for when making a decision to use BGP. You should use BGP in the following cases: You are an ISP and need to pass client traffic from one AS to another AS. You need to multi-home to several ISPs because of company requirements. Traffic flow between your company and other companies must be carefully managed and controlled. You should not use BGP in the following cases: You do not need to have more than one connection to the Internet, or, in the event of multiple connections, you do not care about optimizing the route to destinations in other ASes. The company network engineers do not understand how BGP works. The routers and physical links to the ISP cannot handle the load of BGP traffic.

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