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Each sort of complex including the free ions has a characteristic electrode reaction rate constant (for example, kcMX., / = 0, 1,. . ., n). Consider the relatively simple case where the chemical reactions of formation and dissociation of the complexes are sufficiently fast so that equilibrium among the complexes, free ions and complexing agent is maintained everywhere in the electrolyte during the electrolysis. The rate of deposition of the metal is then determined by the electrode reaction of the complex MX,-, for which the product kcMX.cMX. is, at the given potential, the largest for all the complexes. 5.6.3 Chemical volume reactions According to the theory developed by R. Brdicka and K. Wiesner, a chemical reaction prior to the electrode reaction acts as the rate-controlling step in the electrode process when the electrode reaction disturbs the chemical equilibrium in solution and renewal of this equilibrium is not sufficiently fast. This effect extends to a certain depth in the solution as concentration changes resulting from the electrode reaction are propagated by diffusion. According to J. Koutecky and R. Brdicka, the differential equation describing diffusion to an electrode with a simultaneous chemical reaction is given by combination of the second Fick law and the equation for the reaction rate (this idea first appeared in a paper by A. Eucken). Consider a system of two substances participating in a reversible reaction B <= A (5.6.9)



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Figure 11.8: PE1 applies an MPLS label to the packet from CE1. The packet is then forwarded through the provider network devices P2 and P3 based entirely on the MPLS label until it arrives at PE2. PE2 removes the label and forwards the packet unchanged to CE2.

with the equilibrium constant K = k2/kl. The substance A is present in a marked excess over substance B (K 1), so that its concentration is practically not changed by the electrode process. The substance B undergoes an irreversible electrode reaction with the rate constant kc = k^ exp [ - anF(E - E ')/RT] (see Eq. 5.2.23). The differential equation and boundary and initial conditions for substance B are dc d^c = D f + Jt^CA-ZCce)





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The MPLS forwarding process begins when packets arrive at the PE router from the CE device. Once the PE device receives the packet, it will initiate a decision process to apply the correct label header. The encapsulation by the MPLS label of the Layer 2 header that is received from the CE device depends on whether a Layer 2 or Layer 3

Ta(110) Ta(lll) Ta(lll)

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VPN service is offered by the carrier (The different types of VPN services are discussed later in this chapter) As discussed previously, in an MPLS network the PE and P devices have some special terminology The first PE router is called the Ingress Label Edge Router (iLER) The iLER encapsulates the customer packets with an MPLS label based on provider-configured policies The intermediate routers (usually P routers) are called Label Switching Routers (LSRs) LSRs make switching decisions that are based on the MPLS label The LSR reads the label in the incoming MPLS frame, makes a switching decision, swaps the label, and then transmits the MPLS frame out of the appropriate port or interface The last PE router on the LSP is the Egress Label Edge Router (eLER) The eLER is the termination point of the LSP, or the end of the tunnel.

is assigned a zero value by convention (as mentioned above, this value is assigned to a point infinitely far away from all the conductors), then we can say that potentials or, and ip are measurable just as if they were absolute values. However, both the inner potential and the Galvani potential difference cannot be measured in the sense of 'absolute' values using purely thermodynamic procedures. As a function of the surface potential %, the electron work function for a given material depends on the state of the surface of that material (adsorption, the presence of surface compounds, etc.). For crystalline substances (see Table 3.1), various crystal faces have various electron work function values, which can be measured for single crystals. For poly crystalline substances, the final value of the electron work function depends on the contribution of the individual crystal faces to the entire area of the phase and the corresponding electron work functions; the final value of the work function, however, is strongly dependent on the experimental method used for the measurement. The electron work function is very important for the physics of the solid phase and for its application to electronics. In electrochemistry, it is especially important for electrode processes involving adsorption of some of the species participating in the electrode reaction. If two different, electrically uncharged phases are brought into contact, then the electrochemical potentials of their electrons become equal (i.e.

The egress LER removes the MPLS label and forwards the customer packets to the CE device As previously mentioned, the CE devices neither know nor need to know about any of the MPLSspecific information The MPLS labels are applied by the iLER as the packets enter the provider network and are removed by the eLER as the packets leave the provider network The entire process is completely transparent to the customer Let s examine the entire process a packet undergoes from the time it leaves the origination CE to the time it arrives at the destination CE device For the purposes of this discussion, we will assume that LDP has already distributed label information to all PE and P routers In Figure 118, CE1 sends a data frame toward CE2 On an Ethernet interface, this is a normal IP datagram that is encapsulated in Ethernet.

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