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As already discussed, OSPF is based on routers exchanging link state information with each other. Two OSPF routers must create an OSPF neighbor adjacency before they can exchange routing information. On point-to-point OSPF networks, neighboring routers automatically become fully adjacent with each other once they detect each other via OSPF Hello updates. For example, in Figure 9.2, r2 becomes fully adjacent



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These equations are used to determine ionic conductivities. The transport numbers thus depend on the mobilities of both the ions of the electrolyte (or of all the ions present). This quantity is therefore not a characteristic of an isolated ion, but of an ion in a given electrolyte. Table 2.2 lists examples of transport numbers. It can be seen from the table that the transport numbers also depend on the electrolyte concentration. The following rules can be derived from experimental data: (a) If the transport number is close to 0.5, it depends only very slightly on the concentration. (b) If the transport number for the cation is less than 0.5, then it decreases with increasing concentration (and, simultaneously, t_>0.5 increases with increasing concentration); and vice versa. These rules are based on the theory of conductivity of strong electrolytes accounting for the electrophoretic effect only (the relaxation effect terms outbalance each other). The methods for determination of transport numbers include the Hittorf method and the concentration cell method (p. 121). The Hittorf method is based on measuring the concentration changes at the anode and cathode during electrolysis. These changes can be found by a sensitive analytical method, e.g. conductometrically for a suitable cell





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with both r1 and r3. All neighbor adjacencies in the point-to-point network are indicated with the arrows in the figure.

Table 2.2 Transport numbers of cations at various concentrations (mol dm" 3 ). Relative accuracy 0.02 per cent. (According to B. E. Conway) c Electrolyte HC1 CH.COONa CH3COOK KNO3 NH4CI KC1 KI KBr AgNO 3 NaCl LiCl CaCl2 |Na 2 SO 4 K2SO4 ^LaCl3 |K 4 Fe(CN) 6 3-K3Fe(CN)6 0 0.8209 0.5507 0.6427 0.5072 0.4909 0.4906 0.4892 0.4849 0.4643 0.3963 0.3364 0.4380 0.386 0.479 0.477 0.01 0.8251 0.5537 0.6498 0.5084 0.4907 0.4902 0.4884 0.4833 0.4648 0.3918 0.3289 0.4264 0.3848 0.4829 0.4625 0.515 0.02 0.8266 0.5550 0.6523 0.5087 0.4906 0.4901 0.4883 0.4832 0.4652 0.3902 0.3261 0.4220 0.3836 0.4848 0.4576 0.555 0.05 0.8292 0.5573 0.6569 0.5093 0.4905 0.4899 0.4882 0.4831 0.4664 0.3876 0.3211 0.4140 0.3829 0.4870 0.4482 0.604 0.475 0.10 0.8314 0.5594 0.6609 0.5103 0.4907 0.4898 0.4883 0.4833 0.4682 0.3854 0.3168 0.4060 0.3828 0.4890 0.4375 0.647 0.491 0.20 0.8337 0.5610 0.5120 0.4911 0.4894 0.4887 0.4841 0.3821 0.3112 0.3953 0.3828 0.4910 0.4233

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Figure 9.2 In order to exchange link state information with each other, neighboring OSPF routers must build an adjacency. OSPF routers that are connected to each other on point-to-point links always form adjacencies. The adjacency process begins once each router sees its own router ID in the Hello packets from the other router. Once routers become adjacent, they exchange full link state tables with each other.

arrangement. Transport numbers can be found by using Eq. (2.4.31) from the overall change in electrolyte contents in the anode and cathode compartments. Correct transport numbers could be obtained from concentration changes in the electrode compartments only if the ions were not hydrated in the aqueous solution. When they are hydrated the accompanying water molecules remain in the electrode compartment during discharge of the ions. Accordingly, the measured decrease in electrolyte concentration at the electrode is greater (or smaller) than would correspond to simple charge transport. If n+ molecules of water are bound to each cation n_ and to each anion, then W moles of water are transported by a charge passage corresponding to 1 F: W = n+t+ - n_t_

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The ash from your G11 has a short duration of around 1/1000 second, which effectively becomes the shutter speed for your subject The background, which is probably soft anyway due to a larger aperture being used, won t suffer terribly from any motion blur For a higher-quality look to nighttime portraits, I deactivate my on-camera ash and switch to using an external Speedlite and illuminate my subject from an angle that produces highlights and shadows that translate into depth in the photo This way, I either use the Speedlite bracket to attach the ash to the camera or trigger the Speedlite wirelessly by mounting the ST-E2 transmitter on the G11..

(2.4.34)

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If the cation is more hydrated, then W is a positive number; if the anion is more hydrated, then W is a negative number and water is transported to the anode. Transport numbers calculated from measured concentration changes involving transport of water by solvated ions are sometimes called Hittorf (//) numbers; those corrected for the transport of water are called true transport numbers (*,-). These two types of transport numbers are related by

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