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161 Consider a galvanic cell consisting of hydrogen and silver chloride electrodes: Pt | H2 | HCl(c) | AgCl(s) | Ag | Pt (3.1.40)



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A VPRN is a class of VPN that allows the connection of multiple sites in a routed domain over a service provider IP/MPLS network. VPRN is a Layer 3 service (as opposed to VPWS and VPLS, which are Layer 2 services). From the customer s perspective, all of the sites appear to be connected to a private routed network that is administered by the service provider for that customer only. Each PE router providing VPRN services maintains a separate IP forwarding table for each VPRN. Each customer of the service provider has its own private IP address space and, therefore, may have overlapping IP addresses.





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In this cell, the following independent phases must be considered: platinum, silver, gaseous hydrogen, solid silver chloride electrolyte, and an aqueous solution of hydrogen chloride. In order to be able to determine the EMF of the cell, the leads must be made of the same material and thus, to simplify matters, a platinum lead must be connected to the silver electrode. It will be seen in the conclusion to this section that the electromotive force of a cell does not depend on the material from which the leads are made, so that the whole derivation could be carried out with different, e.g. copper, leads. In addition to Cl~ and H 3 O + ions (further written as H + ), the solution also contains Ag + ions in a small concentration corresponding to a saturated solution of silver chloride in hydrochloric acid. Thus, the following scheme of the phases can be written (the parentheses enclose the species present in the given phase):

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The VPRN service uses VPN Routing and Forwarding Instances (VRFs) within the PE device to maintain forwarding information on a per-customer basis. A VRF is a logical private forwarding (routing) table that securely isolates the routing information of one customer from the next customer, and also from the routes of the Provider Core network. Each PE maintains multiple separate VRFs that are based on the number of distinct VPRN services that the PE supports. Each CE router becomes a routing peer of the provider PE router that it is directly connected to. Routes are exchanged between the CE and the PE routers. The PE devices in a VPRN service exchange routes with each other so that the routes can be transmitted to the remote CE devices of the customer. This process is illustrated in Figure 11.14. Note that Customer 1 and Customer 2 are using the same IP address space, but the PE routers are able to handle this through the use of separate VRF routing tables.

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-,Ag + )|AgCl(Ag + ,C1")l Ag(Ag+ ,e) 1 Pt(e) (3.1.41)

Figure 11.14: A VPRN provides a virtual routed network connection for multiple customers. Each customer can have its own private address space, and the PE will maintain a separate VRF for each customer to separate the IP addressing.

The electrodes employed will be considered in greater detail in Section 3.2. Here it is sufficient that this cell can yield electrical energy, because the cell reaction ^H2(2) + AgCl(4)-> H+(3) + CT(3) + Ag(5) (3.1.42)

CE1 Customer 1 VPRN 100 CE2 PE1 PE2 192.168.3.0/24 192.168.3.0/24

takes place spontaneously. Depending on the processes occurring during the cell reaction at the individual electrodes, the cell reaction can be separated into two half-cell reactions formulated as reduction by electrons. For the cell reaction described by Eq. (3.1.42), these reactions are AgCl(4) + e = Ag(5) + Cl~(3) H (3) + e = iH2(2)

192.168.1.0/24 192.168.2.0/24 192.168.1.0/24

(3.1.43) (3.1.44)

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