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Figure 11.13: In a VPLS, the PE devices maintain an FDB to keep track of MAC addresses, service IDs, and SAPs. The PEs will tag the packets with the appropriate service ID and MPLS label for forwarding through the MPLS network.



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(c) (d)

VPLS service 100 IP = 192.168.0.1/24 MAC = 00:03:fa:00:00:01 CE1 SAP 1/1/1 CE3 IP = 192.168.1.2/24 MAC = 00:03:fa:00:00:02 P2 PE1 P1 PE2 VPLS service 100 CE2

Thus, Eq. (c) corresponds to scheme (a) and Eq. (d) to scheme (b). The flow of the charge is due to the chemical forces described by the affinity of the cell reaction, and at the same time to the electrical forces measured by the electrical potential difference. The affinity of the reaction is given by the algebraic sum of the chemical potentials of all the substances participating in the reaction multiplied by the corresponding stoichiometric coefficients (which are positive for reactants and negative for products); it is thus given by the decrease in the Gibbs free energy of the system AG. The sign of the affinity, however, is reversed when the reaction is written in the opposite direction. Thus, for reactions (c) and (d), -AGc=+AGd (3.1.38)

SAP 1/1/1

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If the reaction in the cell proceeds to unit extent, then the charge nF corresponding to integral multiples of the Faraday constant is transported through the cell from the left to the right in its graphical representation. Factor n follows from the stoichiometry of the cell reaction (for example n = 2 for reaction c or d). The product nFE is the work expended when the cell reaction proceeds to a unit extent and at thermodynamic equilibrium and is equal to the affinity of this reaction. Thus,

SAP 1/1/2

(3.1.39)

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PE1 Service FDB Source MAC Service ID 00:03:fa:00:00:01 SAP 1/1/1 100 00:03:fa:00:00:02 SAP 1/1/2 100 00:03:fa:00:00:03 SDP 21:100 100

Considering that (-AG d ) > 0 when ( AGC) < 0, then it is apparent that the sign of the EMF depends on the direction in which the scheme of the cell is written and, consequently, on the direction in which the reaction is written. The EMF is positive when the reaction and the scheme are formulated so as to correspond to a spontaneous reaction (the reaction would occur spontaneously in the direction indicated if the cell were short-circuited). Thus cell (a) has a positive EMF and cell (b) a negative one.

PE2 Service FDB MAC Source Service ID 00:03:fa:00:00:03 SAP 1/1/1 100 100 00:03:fa:00:00:01 SDP 21:100 100 00:03:fa:00:00:02 SDP 21:100

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